Výsledky vyhledávání - "Fausto Calderazzo"

Homonuclear and heteronuclear transition metal complexes by syn-proportionation reactions

Autor: Guido Pampaloni, Fausto Calderazzo, Masi Francesco

Publikováno v: Inorganica Chimica Acta. 362:4291-4297

Redox processes consisting of disproportionation and syn-proportionation are reviewed with special attention to metal complexes containing carbon-based ligands, i.e. carbon monoxide or unsaturated hydrocarbons. An introduction and a survey of reactio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::124418d49610ce8684444c0ee3771dac
https://doi.org/10.1016/j.ica.2009.05.053

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Nanostructured Copper Oxide on Silica-Zirconia Mixed Oxides by Chemical Implantation

Autor: Silvia Gross, Bernd M. Smarsly, Massimiliano D’Arienzo, Helmut Bertagnolli, Eugenio Tondello, Daniela Belli Dell'Amico, Eric Wendel, Ralf Supplit, Roberto Scotti, Luca Labella, Fausto Calderazzo, Marzio Rancan

Publikováno v: Chemistry 15, 4931 (2009). doi:10.1002/chem.200801704
Chemistry (Weinh., Print) 15 (2009): 4931–4943. doi:10.1002/chem.200801704
info:cnr-pdr/source/autori:Dell'Amico, D. B.; Bertagnolli, H.; Calderazzo, F.; D'Arienzo, M.; Gross, S.; Labella, L.; Rancan, M.; Scotti, R.; Smarslu, B. M.; Supplit, R.; Tondello, E.; Wendel, E./titolo:Nanostructured Copper Oxide on Silica-Zirconia Mixed Oxides by Chemical Implantation/doi:10.1002%2Fchem.200801704/rivista:Chemistry (Weinh., Print)/anno:2009/pagina_da:4931/pagina_a:4943/intervallo_pagine:4931–4943/volume:15

N,N-Dialkylcarbamato complexes of copper(II), [Cu(O2CNR2)2] (R = All = allyl, C3H5; iPr, CH(CH3)2) were prepared with the aim of func-tionalizing silica and nanostructured silica-zirconia matrices. The mixed matrices for the grafting reactions were p

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https://doi.org/10.1002/chem.200801704

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N,N-Di-iso-propylcarbamato Complexes of Boron

Autor: Fausto Calderazzo, Daniela Belli Dell'Amico, Fabio Marchetti, Luca Labella

Publikováno v: Inorganic Chemistry. 47:5372-5376

N,N-di- iso-propylcarbamato derivatives of boron(III) have been synthesized from di-iso-propylamine and boron trichloride in the presence of carbon dioxide. With a large excess of amine, a single boron product was obtained, [NH2i)Pr2][B(O2CNiPr2)4],

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https://doi.org/10.1021/ic7024523

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Simple Preparations of Pd6Cl12, Pt6Cl12, and Qn[Pt2Cl8+n], n = 1, 2 (Q = TBA+, PPN+) and Structural Characterization of [TBA][Pt2Cl9] and [PPN]2[Pt2Cl10]·C7H8

Autor: Fausto Calderazzo, Fabio Marchetti, Simona Samaritani, Daniela Belli Dell'Amico, Stefano Ramello

Publikováno v: Inorganic Chemistry. 47:1237-1242

The hexanuclear Pd6Cl12, i.e., the crystal phase classified as β-PdCl2, was obtained by reacting [TBA]2[Pd2Cl6] with AlCl3 (or FeCl3) in CH2Cl2. The action of AlCl3 on PtCl42-, followed by digestio...

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https://doi.org/10.1021/ic701932u

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Competitive ligation between carbon monoxide and propiononitrile in chloro-complexes of platinum(II)

Autor: Laura Carbonaro, Daniela Belli Dell'Amico, Stefano Libri, Luca Labella, Fausto Calderazzo, Fabio Marchetti

Publikováno v: Inorganica Chimica Acta. 360:3765-3770

EtCN partially displaces coordinated carbon monoxide from cis-PtCl2(CO)2 giving an equilibrium mixture of the two geometrical isomers of PtCl2(CO)(NCEt), together with unreacted cis-PtCl2(CO)2, as monitored by IR and NMR measurements. The equilibrium

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https://doi.org/10.1016/j.ica.2007.05.019

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A trinuclear anionic trifluoroacetato derivative of iron(II) containing a central O(–I) ligand

Autor: Bernardo Melai, Guido Pampaloni, Fausto Calderazzo, Silvia Rizzato, Sax A. Mason, Fabio Marchetti, Alberto Albinati

Publikováno v: Inorganic Chemistry Communications. 10:902-905

The reaction of Fe(CO)5 with CF3COOH/(CF3CO)2O, or with CF3COOH, in DMF at about 140 °C produces the colourless compound 1, [Fe(DMF)6][Fe3(μ3-O) (CF3COO)6(DMF)3]2, constituted by the [Fe(DMF)6]2+ cation and by two [Fe3(μ3-O)(μ2-CF3COO)6(DMF)3]−

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https://doi.org/10.1016/j.inoche.2007.03.035

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Coordination properties towards palladium(II) of a tridentate dianionic ligand acting as a N- or a N,O-donor

Autor: Gianfranco Guglielmetti, Luca Labella, Fabio Marchetti, Francesco Di Colo, Fausto Calderazzo, Daniela Belli Dell'Amico

Publikováno v: Inorganica Chimica Acta. 359:127-135

The new palladium(II) complex Pd[C5H3N-2,6-(CONPh)2](η1-NCMe) (1), prepared from N,N′-diphenyl-2,6-pyridinedicarboxamide and Pd(OAc)2 in acetonitrile, has been characterized via IR, 1H NMR and single-crystal X-ray diffraction. In this compound the

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https://doi.org/10.1016/j.ica.2005.06.073

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Competition between Carbon Monoxide and Alkenes in Chloro Complexes of Platinum(II)

Autor: Fausto Calderazzo, Anna Vitullo, Daniela Belli Dell'Amico, Laura Carbonaro, Riccardo Bini, Luca Labella

Publikováno v: Organometallics. 24:4427-4431

Alkenes (cyclohexene; 1-octene) and dienes (cyclooctadiene, COD; norbornadiene, NBD) react with cis-PtCl2(CO)2, leading, respectively, to partial and complete displacement of coordinated carbon monoxide. Equilibrium constants at 21 °C in 1,2-dichlor

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https://doi.org/10.1021/om050325u

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Redox reactions with bis(η6-arene) derivatives of early transition metals

Autor: Guido Pampaloni, Ulli Englert, Fausto Calderazzo, Manuel Volpe

Publikováno v: Journal of Organometallic Chemistry. 690:3321-3332

The reactivity of M(η 6 -arene) 2 derivatives of early transition metals (M = Ti, Cr, Mo, arene = MeC 6 H 5 ; M = V, Nb, arene = 1,3,5-Me 3 C 6 H 3 ) has been investigated and the syntheses of new and known compounds are described. The derivatives M

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https://doi.org/10.1016/j.jorganchem.2005.03.064

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