In Situ Solution-State Characterization of MOF-Immobilized Transition-Metal Complexes by Infrared Spectroscopy

Autor: Sherzod T. Madrahimov, Ashfaq A. Bengali, Palani Elumalai, Manyam Praveen Kumar, Farida H. Aidoudi, Hind Mamlouk

Publikováno v: ACS Applied Materials & Interfaces. 12:3171-3178

Transition-metal catalysts immobilized on the surface of Metal-organic frameworks (MOFs) are being utilized for an ever-increasing number of reactions ranging from couplings to olefin oligomerization. While these reactions are usually performed in so

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5abf75823c012dfdf81d14c1bbd458a6
https://doi.org/10.1021/acsami.9b18099

Extending the Family of V4+S=${{ 1/2 }}$ Kagome Antiferromagnets

Autor: Alexandra M. Z. Slawin, Russell E. Morris, Lucy Clark, Philip Lightfoot, Farida H. Aidoudi, Cameron Black, Kasun S. Athukorala Arachchige

Publikováno v: Angewandte Chemie. 127:15677-15681

The ionothermal synthesis, structure, and magnetic susceptibility of a novel inorganic-organic hybrid material, imidazolium vanadium(III,IV) oxyfluoride [CHN][VOF(HO)] (ImVOF) are presented. The structure consists of inorganic vanadium oxyfluoride sl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::42c91691c3e9a549cdeee70b03a8cc41
https://doi.org/10.1002/ange.201506869

An ionothermally prepared S = 1/2 vanadium oxyfluoride kagome lattice

Autor: Farida H. Aidoudi, Russell E. Morris, Richard J. Goff, Alexandra M. Z. Slawin, David W. Aldous, Philip Lightfoot, J. Paul Attfield

Publikováno v: Nature Chemistry. 3:801-806

Frustrated magnetic lattices offer the possibility of many exotic ground states that are of great fundamental importance. Of particular significance is the hunt for frustrated spin-1/2 networks as candidates for quantum spin liquids, which would have

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5a2b369c0dfeaa6d77851de61a123ac7
https://doi.org/10.1038/nchem.1129

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Autor: Mark A. de Vries, Philip Lightfoot, Russell E. Morris, Lewis J. Downie, Farida H. Aidoudi

Publikováno v: Aidoudi, F H, Downie, L J, Morris, R E, A. De Vries, M & Lightfoot, P 2014, ' A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers ', Dalton Transactions, vol. 43, no. 17, pp. 6304-6307 . https://doi.org/10.1039/c4dt00452c

A new organically-templated vanadium (III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The co

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9520f10799620ca38a3960a3cf391b95
https://pubmed.ncbi.nlm.nih.gov/24626600

Gapless Spin Liquid Ground State in theS=1/2Vanadium Oxyfluoride Kagome Antiferromagnet[NH4]2[C7H14N][V7O6F18]

Autor: Farida H. Aidoudi, Andrew Harrison, M. A. de Vries, Russell E. Morris, Pierre Bonville, Mark T. F. Telling, James S. Lord, Philip Lightfoot, Philippe Mendels, Fabrice Bert, J. C. Orain, J. P. Attfield, Lucy Clark

Publikováno v: Physical Review Letters. 110

The vanadium oxyfluoride [NH(4)](2)[C(7)H(14)N][V(7)O(6)F(18)] (DQVOF) is a geometrically frustrated magnetic bilayer material. The structure consists of S = 1/2 kagome planes of V(4+) d(1) ions with S = 1 V(3+) d(2) ions located between the kagome l

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d869abbd425a6dccbb4138b5e1f7c3d5
https://doi.org/10.1103/physrevlett.110.207208