Zobrazeno 1 - 10
of 43
pro vyhledávání: '"Faraj, Hasanayn"'
Publikováno v:
Organometallics. 41:3426-3434
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::93e627a028a00f25736e94315600a012
https://doi.org/10.1021/acs.organomet.2c00401
https://doi.org/10.1021/acs.organomet.2c00401
The para-N-pyridyl-based PCP pincer ligand 3,5-bis(di-tert-butylphosphinomethyl)-2,6-dimethylpyridine (pN-tBuPCP-H) was synthesized and metalated to give the iridium complex (pN tBuPCP)IrHCl (2-H). In marked contrast with its phenyl-based congeners (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb0209096cac7260affc748ef8a7cc69
https://doi.org/10.26434/chemrxiv-2023-8sbll
https://doi.org/10.26434/chemrxiv-2023-8sbll
The activation of dinitrogen by coordination to transition metal ions is a widely used and promising approach to the utilization of Earth’s most abundant nitrogen source for chemical synthesis. End-on bridging N2 complexes (µ-N2) are key species i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c5465aa59c428d0048545138e3facc58
https://doi.org/10.26434/chemrxiv-2022-p3nrk
https://doi.org/10.26434/chemrxiv-2022-p3nrk
Autor:
Matthew R. Espinosa, Mehmed Z. Ertem, Mariam Barakat, Quinton J. Bruch, Anthony P. Deziel, Matthew R. Elsby, Faraj Hasanayn, Nilay Hazari, Alexander J. M. Miller, Matthew V. Pecoraro, Allison M. Smith, Nicholas E. Smith
Publikováno v:
Journal of the American Chemical Society. 144(39)
The kinetics of hydride transfer from Re(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::10bf784a5d8683215aa9c674729c7b18
https://pubmed.ncbi.nlm.nih.gov/36130605
https://pubmed.ncbi.nlm.nih.gov/36130605
Autor:
Alan S. Goldman, Patrick L. Holland, Alexander J. M. Miller, Mohamad Ataya, Faraj Hasanayn, Lynn S. Yamout
Publikováno v:
Journal of the American Chemical Society. 143:9744-9757
Terminal and bridging end-on coordination of N2 to transition metal complexes offer possibilities for distinct pathways in ammonia synthesis and N2 functionalization. Here we elucidate the fundamental factors controlling the two binding modes and det
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2fdbe777efc4adcc7bf0c81a17c50ee3
https://doi.org/10.1021/jacs.1c01146
https://doi.org/10.1021/jacs.1c01146
Autor:
Brandon Q. Mercado, Jeremy E. Weber, Faraj Hasanayn, Robert H. Crabtree, Majed Fataftah, Patrick L. Holland
Publikováno v:
Inorganic Chemistry. 60:6115-6124
Bimetallic nitrogen (N2) splitting to form metal nitrides is an attractive method for N2 fixation. Although a growing number of pincer-supported systems can bind and split N2, the precise relationship between the ligand properties and N2 binding/spli
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44d019f7caa32840ce5c01c66ce7b051
https://doi.org/10.1021/acs.inorgchem.0c03778
https://doi.org/10.1021/acs.inorgchem.0c03778
Autor:
Mohamad Ataya, Faraj Hasanayn
Publikováno v:
Canadian Journal of Chemistry. 99:236-244
The octahedral trans hydrido-alkoxide complex trans-(H)(OMe)-Ir(Ph)(PMe3)3 (2-OCH3) was prepared by Milstein and coworkers by addition of methanol to Ir(Ph)(PMe3)3 (1). 2-OCH3 was discovered to undergo a methanol catalyzed outer-sphere carbonyl de-in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::38a72d976505f6d2791cb5a732f843fa
https://doi.org/10.1139/cjc-2020-0313
https://doi.org/10.1139/cjc-2020-0313
Autor:
Gannon P. Connor, Alan S. Goldman, Alexander J. M. Miller, Quinton J. Bruch, Noah D. McMillion, Faraj Hasanayn, Patrick L. Holland
Publikováno v:
ACS Catalysis. 10:10826-10846
Despite advances in the development of molecular catalysts capable of reducing dinitrogen to ammonia using proton donors and chemical reductants, few molecular electrocatalysts have been discovered...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::317736579d3aa9a989c9a18e9a781435
https://doi.org/10.1021/acscatal.0c02606
https://doi.org/10.1021/acscatal.0c02606
Publikováno v:
Organometallics. 39:286-294
The tripodal ligated octahedral complex d6-[Rh(PhB(CH2PPh2)3)(H)2(NCMe)] (1-RhH) was discovered by Tejel and co-workers to catalyze the Tishchenko reaction in which two aldehydes are dimerized into...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e70503df8df516c8e445c2688757a4d5
https://doi.org/10.1021/acs.organomet.9b00622
https://doi.org/10.1021/acs.organomet.9b00622
The selective functionalization of alkanes and alkyl groups is a major goal of chemical catalysis. Toward this end, a bulky triphosphine with a central secondary phosphino group, bis(2 di-t-butyl-phosphinophenyl)phosphine (tBuPHPP), has been synthesi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::37104b2347f945eaf0ca96db0fb14ca4
https://doi.org/10.26434/chemrxiv-2021-mqjrc
https://doi.org/10.26434/chemrxiv-2021-mqjrc