Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Fabienne Ramirez-Vega"'
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 96:15-20
Reactive chlorides ZCH 2 Cl (Z = C 6 H 5 , CH 3 OC(O), CN) are readily carbonylated into esters with methyl formate as the sole source of carbon monoxide and methanol, the tetracarbonyl cobaltate anion as the catalyst and sodium carbonate as the base
Publikováno v:
Tetrahedron Letters. 34:8117-8118
Some phophines and aliphatic amines are efficient in decarbonylating formate esters. Simple amines in the presence of DMF as well as some aminoalcohols decarbonylate methyl formate efficiently at 190°C. Likewise, formate esters are decarbonylated by