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Publikováno v:
Tetrahedron Letters. 41:4219-4222
Tricarbonyliron complexes of α-methoxyheptadienone 3 and octadienone 8 were reacted as silyl enol ethers with protected β-hydroxypropanal and TiCl4, to give the syn–syn aldol condensation products 4 and 11 as major, isolated diastereomers (61 and
Publikováno v:
ChemInform. 31
Publikováno v:
ChemInform. 31
Tricarbonyliron complexes of α-substituted dienones are well suited starting compounds for the synthesis of diastereomerically pure 1,2,3-trisubstituted 1,3-diols of known configuration, among them 1,2,3-triols. This is achieved by aldol condensatio