Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Fabian Uhlemann"'
Autor:
Fabian Uhlemann, Andreas Schnepf
Publikováno v:
Chemistry - A European Journal. 22:10748-10753
The reaction of a metastable SiCl2 solution with the sterically less-demanding carbene N,N-diisopropylimidazo-2-ylidene (IPr) yields the salt [(IPr3 Si3 Cl5 )(+) ]Cl(-) (1-Cl), containing a silyl cation with a Si3 backbone. Salt 1 is highly reactive,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c7244424862303b217812a4a2fb8a5b4
https://doi.org/10.1002/chem.201601728
https://doi.org/10.1002/chem.201601728
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 640:1658-1664
Thermodynamic data for gaseous SiF2 and SiCl2 known from literature show that these binary subhalides are formed nearly quantitatively at 1376 °C and 1076 °C, respectively, as products of the reaction of elemental silicon with SiF4 or SiCl4 at 110
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1d0a0923626f140eedf3a7f1d028268a
https://doi.org/10.1002/zaac.201400122
https://doi.org/10.1002/zaac.201400122
Publikováno v:
ChemInform. 45
SiF2 (I) as well as SiCl2 (II) are prepared in the gas phase from Si and SiF4 (SiCl4) at 1510 °C (I) resp.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d48cc5375737de2688965dffcb47fed4
https://doi.org/10.1002/chin.201436012
https://doi.org/10.1002/chin.201436012