Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Fabian Keppner"'
Autor:
Johannes Landmann, Tanja Knuplez, Christoph Kerpen, Nikolai V. Ignat'ev, Ludwig Zapf, Rüdiger Bertermann, Kristina A. M. Maibom, Tobias Bischof, Fabian Keppner, Eva-Maria Tanzer Krauel, Carl Deutsch, Leon Schneider, Klaus Urbahns, Michael Hailmann, Maik Finze
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Fluorinated groups are essential for drug design, agrochemicals, and materials science. The bis(trifluoromethyl)amino group is an example of a stable group that has a high potential. While the number of molecules containing perfluoroalkyl, perfluoroa
Autor:
Nikolai V. Ignat'ev, Maik Finze, Christoph Kerpen, Holger Braunschweig, Fabian Keppner, Jan A. P. Sprenger, Tatjana Ribbeck, Merle Arrowsmith, Christian Schmidle
Publikováno v:
Inorganic Chemistry. 58:16689-16702
In recent years, salts of the hydridotricyanoborate anion [BH(CN)3]- (MHB) have become readily available. In spite of the unusually high stability of the MHB anion, it can be used as a valuable starting material for the preparation of selected tricya
Autor:
Sotiris S. Xantheas, Szymon Z. Konieczka, Christoph Kerpen, Gao-Lei Hou, Michael Deckert, Julia Laskin, Grant E. Johnson, Edoardo Aprà, Thomas Schäfer, Maik Finze, Zheng Yang, Xue-Bin Wang, Fabian Keppner, Eric J. Bylaska, Jonas Warneke
Publikováno v:
Physical Chemistry Chemical Physics. 21:5903-5915
closo-Borate anions [closo-BnXn]2− are part of the most famous textbook examples of polyhedral compounds. Substantial differences in their reactivity and interactions with other compounds depending on the substituent X and cluster size n have been
Autor:
Sven H. Zottnick, Nikolai V. Ignat'ev, Fabian Keppner, Maik Finze, Daniel B. Hofmann, Klaus Müller-Buschbaum, Johannes Landmann, Jan A. P. Sprenger, Mathias Häring
Publikováno v:
Angewandte Chemie. 129:2839-2843
Die Reaktionen von [BH(CN)3]− mit starken nicht-nucleophilen Basen sind die ersten Beispiele fur die Deprotonierung eines Hydridoborat-Anions. Diese liefern Alkalimetall-Salze mit dem Tricyanoborat-Dianion B(CN)32− in bis zu 97 % Ausbeute und 99.
Autor:
Andreas Steffen, Philipp T. Hennig, Alexander Himmelspach, Rüdiger Bertermann, Michael Hailmann, Maik Finze, Fabian Keppner, Benjamin Hupp
Publikováno v:
Chemical communications (Cambridge, England). 55(63)
A set of mono- and dinuclear AuI and AgI alkynyl complexes bearing the carba-closo-dodecaboranylethynyl ligand show intense room temperature phosphorescence. The {closo-1-CB11} cage participates in an unprecedented way as an electron donating moiety,
Autor:
Jonas, Warneke, Szymon Z, Konieczka, Gao-Lei, Hou, Edoardo, Aprà, Christoph, Kerpen, Fabian, Keppner, Thomas C, Schäfer, Michael, Deckert, Zheng, Yang, Eric J, Bylaska, Grant E, Johnson, Julia, Laskin, Sotiris S, Xantheas, Xue-Bin, Wang, Maik, Finze
Publikováno v:
Physical chemistry chemical physics : PCCP. 21(11)
closo-Borate anions [closo-BnXn]2- are part of the most famous textbook examples of polyhedral compounds. Substantial differences in their reactivity and interactions with other compounds depending on the substituent X and cluster size n have been re
Autor:
Klaus Müller-Buschbaum, Nikolai V. Ignat'ev, Daniel B. Hofmann, Maik Finze, Fabian Keppner, Sven H. Zottnick, Johannes Landmann, Mathias Häring, Jan A. P. Sprenger
Publikováno v:
Angewandte Chemie (International ed. in English). 56(10)
The first deprotonation of a borohydride anion was achieved by treatment of [BH(CN)3]− with strong non-nucleophilic bases, which resulted in the formation of alkali-metal salts of the tricyanoborate dianion B(CN)32− in up to 97 % yield and 99.5 %