Zobrazeno 1 - 10
of 557
pro vyhledávání: '"FRANK W. HEINEMANN"'
Cooperative spin crossover leading to bistable and multi-inert system states in an iron(III) complex
Autor:
Andreas Dürrmann, Gerald Hörner, Dirk Baabe, Frank W. Heinemann, Mauricio A. C. de Melo, Birgit Weber
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-13 (2024)
Abstract Cooperativity among spin centres has long been the royal road in spin crossover (SCO) research to impose magnetic bistability in terms of thermal hysteresis. In this work we access magnetic multi-inert states of the iron(III) compound {FeL2[
Externí odkaz:
https://doaj.org/article/74bca1af92d140eca9b5dc34f83e3f19
Autor:
Andrey G. Lvov, Max Mörtel, Anton V. Yadykov, Frank W. Heinemann, Valerii Z. Shirinian, Marat M. Khusniyarov
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 2428-2437 (2019)
A new family of photochromic diarylethene-based ligands bearing a 2-(imidazol-2-yl)pyridine coordination unit has been developed. Four members of the new family have been synthesized. The photoactive ligands feature non-aromatic ethene bridges (cyclo
Externí odkaz:
https://doaj.org/article/23ac87dbcbaa4988a06d3c069ed6c9f9
Autor:
Julian Messelberger, Annette Grünwald, Philipp Stegner, Laura Senft, Frank W. Heinemann, Dominik Munz
Publikováno v:
Inorganics, Vol 7, Iss 5, p 65 (2019)
The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor properties can be a challenging task. This is due to the dimerization of free carbene ligands, the moisture sensitivity of reaction intermediates or reage
Externí odkaz:
https://doaj.org/article/ec35c9f9cf5d45a695424953c16d0bbd
Autor:
VERICA V. GLODJOVIĆ, GORDANA P. RADIĆ, SNEŽANA M. STANIĆ, FRANK W. HEINEMANN, SREĆKO R. TRIFUNOVIĆ
Publikováno v:
Journal of the Serbian Chemical Society, Vol 76, Iss 7, Pp 995-1001 (2011)
(S,S)-Ethylenediamine-N,N’-di-2-propanoic acid hydrochloride, (S,S)-H2eddp·HCl, was prepared and its crystal structure determined. The compound was characterized by infrared and 1H- and 13C-NMR spectroscopy. It forms P1 in the space group of a tri
Externí odkaz:
https://doaj.org/article/1c23937ae1e4427abb4696c049a9c9a7
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 7, Pp o824-o824 (2014)
In the title compound, alternatively called α-hydroxy-γ-alkylidenebutenolide, C12H16O3, two independent molecules (A and B) crystallize in the asymmetric unit in each of which the 5,6-dihydrobenzo ring has an envelope conformation. The torsion angl
Externí odkaz:
https://doaj.org/article/411091a9fa514f7cb749e706aa8fb318
Autor:
Douglas R. Hartline, Sascha T. Löffler, Dominik Fehn, Joseph M. Kasper, Frank W. Heinemann, Ping Yang, Enrique R. Batista, Karsten Meyer
Publikováno v:
Journal of the American Chemical Society. 145:8927-8938
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b8b84be567860c3f726329506a9080fe
https://doi.org/10.1021/jacs.2c12868
https://doi.org/10.1021/jacs.2c12868
Publikováno v:
Inorganic Chemistry. 62:2013-2023
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7e57086a80ee775c201305f5083e6ad4
https://doi.org/10.1021/acs.inorgchem.2c03520
https://doi.org/10.1021/acs.inorgchem.2c03520
Autor:
Martin Keilwerth, Weiqing Mao, Sergio A. V. Jannuzzi, Liam Grunwald, Frank W. Heinemann, Andreas Scheurer, Jörg Sutter, Serena DeBeer, Dominik Munz, Karsten Meyer
Publikováno v:
Journal of the American Chemical Society. 145:873-887
As key intermediates in metal-catalyzed nitrogen-transfer chemistry, terminal imido complexes of iron have attracted significant attention for a long time. In search of versatile model compounds, the recently developed second-generation
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9a24da30ffaf0274936363a9822891e
https://doi.org/10.1021/jacs.2c09072
https://doi.org/10.1021/jacs.2c09072
Autor:
Annette Grünwald, Bhupendra Goswami, Kevin Breitwieser, Bernd Morgenstern, Martí Gimferrer, Frank W. Heinemann, Dajana M. Momper, Christopher W. M. Kay, Dominik Munz
Publikováno v:
Journal of the American Chemical Society. 144:8897-8901
Whereas triplet-nitrene complexes of the late transition metals are isolable and key intermediates in catalysis, singlet-nitrene ligands remain elusive. Herein we communicate three such palladium terminal imido complexes with singlet ground states. U
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::75f1691493ba58bff545324c5e6e3734
https://doi.org/10.1021/jacs.2c02818
https://doi.org/10.1021/jacs.2c02818
Autor:
Sibylle Frieß, Anna Benyak, Alberto Herrera, Ana M. Escalona, Frank W. Heinemann, Jens Langer, Dominik Fehn, Daniel Pividori, Alexander Grasruck, Dominik Munz, Karsten Meyer, Romano Dorta
Publikováno v:
Inorganic Chemistry. 61:1236-1248
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1be9a64e6b4f4b0d809ce22890877cb2
https://doi.org/10.1021/acs.inorgchem.1c02956
https://doi.org/10.1021/acs.inorgchem.1c02956