Zobrazeno 1 - 10
of 15
pro vyhledávání: '"F. W. J. Demnitz"'
Publikováno v:
Organic Letters. 2:3313-3316
Acrylate 4, prepared from diacetylrhamnal, underwent intramolecular Diels-Alder cycloaddition to give the thermodynamically disfavored trans-fused gamma-lactone 15 as the major product, along with two stereoisomeric cycloadducts. A computational anal
Publikováno v:
ChemInform. 26
Publikováno v:
ChemInform. 26
Autor:
P. Ciceri, F. W. J. Demnitz
Publikováno v:
ChemInform. 28
Autor:
R. A. Raphael, F. W. J. Demnitz
Publikováno v:
ChemInform. 28
Publikováno v:
ChemInform. 29
Autor:
F. W. J. Demnitz, M. B. D'heni
Publikováno v:
ChemInform. 29
Synthesis of an advanced intermediate for (+)-pillaromycinone. Staunton-Weinreb annulation revisited
Publikováno v:
Organic letters. 10(13)
Condensation of an orsellinate anion with a 2-cyclohexenone (Staunton−Weinreb annulation) afforded a linear tetracycle which was converted to a protected derivative of 12a-epipillaromycinone. Methodology for introducing a 12a-hydroxyl substituent i
Publikováno v:
ChemInform. 32
Acrylate 4, prepared from diacetylrhamnal, underwent intramolecular Diels−Alder cycloaddition to give the thermodynamically disfavored trans-fused γ-lactone 15 as the major product, along with two stereoisomeric cycloadducts. A computational analy
Autor:
F. W. J. Demnitz
Publikováno v:
ChemInform. 21
Ketene bis(trimethylsilyl) acetals were reacted with α-halo acetals giving β-alkoxy-γ-halo acids which were converted to butenolides by reaction with two equivalents of base. This constitutes a novel and short butenolide synthesis.