Zobrazeno 1 - 10
of 14
pro vyhledávání: '"F. W. H. Kruger"'
Autor:
C. W. Holzapfel, F. W. H. Kruger
Publikováno v:
ChemInform. 23
The chiral synthesis of the fungal metabolite β- cyclopiazonic acid is described. The key step involves the use of the tricarbonylchromium complex of an N-protected L- tryptophan methyl ester as a substrate for the addition/oxidation method of subst
Autor:
F. W. H. Kruger, W. J. McGill
Publikováno v:
Journal of Applied Polymer Science. 45:1545-1556
Several aspects on the mechanism of vulcanization in the synthetic cis-1,4-polyisoprene (IR)-sulfur-tetramethylthiuram disulphide (TMTD)–ZnO system were harmonized. The differential scanning calorimetry (DSC) thermograms showed that the vulcanizati
Autor:
F. W. H. Kruger, W. J. McGill
Publikováno v:
Journal of Applied Polymer Science. 45:1491-1495
The network maturing reactions of the inefficient cis-1,4-polyisoprene (IR)–sulfur–zinc dimethyldithiocarbamate (ZDMC) and IR–sulfur–ZDMC–ZnO vulcanization systems were discussed. The Moore–Trego efficiency E was exceptionally high and in
Autor:
F. W. H. Kruger, W. J. McGill
Publikováno v:
Journal of Applied Polymer Science. 45:749-753
During the vulcanization of cis-1,4-polyisoprene (IR) with thiruam-related curing systems, dimethyldithiocarbamic acid (DMDCA) is formed as a byproduct, in the formation of either pendent groups or crosslinks. DMDCA is unstable, and decomposes instan
Autor:
W. J. McGill, F. W. H. Kruger
Publikováno v:
Journal of Applied Polymer Science. 45:755-763
Aspects of the mechanism of zinc dimethyldithiocarbamate (ZDMC)-accelerated sulfur vulcanization were discussed. The trends in the efficiency parameter E, confirmed that crosslinking is preceded by the formation of pendent groups RSxSX [R = polyisopr
Autor:
W. J. McGill, F. W. H. Kruger
Publikováno v:
Journal of Applied Polymer Science. 45:573-578
Several aspects concerning the network maturing reactions of the cis-1,4-polyisoprene (IR)/tetramethylthiuram disulfide (TMTD)/ZnO curing system, were evaluated with reference to previously published literature. The crosslink density increased progre
Autor:
W. J. McGill, F. W. H. Kruger
Publikováno v:
Journal of Applied Polymer Science. 45:563-571
A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (IR)-tetramethylthluram disulfide (TMTD)–ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mecha
Autor:
W. J. McGill, F. W. H. Kruger
Publikováno v:
Journal of Applied Polymer Science. 44:587-592
The interaction of curatives in the systems cis-1,4-polyisoprene (IR)–sulfur, IR–sulfur–ZnO, IR–tetramethylthiuram disulphide (TMTD), and IR–sulfur–TMTD were studied. Thermal events observed in the differential scanning calorimetry curing
Autor:
F. W. H. Kruger, W. J. McGill
Publikováno v:
Journal of Applied Polymer Science. 44:581-585
The tetramethylthiuram disulfide (TMTD) and zinc dimethyldithiocarbamate (ZDMC) related vulcanization of cis-1,4-polyisoprene (IR) were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and electron spin resonance
Autor:
F. W. H. Kruger, W. J. McGill
Publikováno v:
Journal of Applied Polymer Science. 42:2661-2667
The interaction among various combinations of sulfur, tetramethylthiuram monosulphide (TMTM), ZnO, and stearic acid were studied by differential scanning calorimetry in the absence of rubber. Sulfur and TMTM reacted to form tetramethylthiuram disulph