Zobrazeno 1 - 10
of 132
pro vyhledávání: '"F. W. B. Einstein"'
Autor:
Sean A. Lumb, Peter Legzdins, F. W. B. Einstein, Raymond J. Batchelor, Jeff D. Debad, Steven J. Rettig
Publikováno v:
Organometallics. 18:3414-3428
Thermal activation of Cp*W(NO)(η2-CPhCH2)(CH2SiMe3) (1) in neat hydrocarbon solutions transiently generates Cp*W(NO)(η2-PhC⋮CH) (A), which subsequently activates solvent C−H bonds. For example, the...
Autor:
Changqing Wang, Helge Willner, Andrew R. Lewis, Raymond J. Batchelor, F. W. B. Einstein, Friedhelm Aubke
Publikováno v:
Inorganic Chemistry. 35:1279-1285
Addition of carbon monoxide (0.5-2 atm) to iridium(III) fluorosulfate, Ir(SO(3)F)(3), dissolved in HSO(3)F over 4 days and at 60 degrees C, results in the quantitative formation of tris(carbonyl)iridium(III) fluorosulfate Ir(CO)(3)(SO(3)F)(3). Slow e
Autor:
Helge Willner, Changqing Wang, Raymond J. Batchelor, Matthias Bodenbinder, G. Balzer-Jöllenbeck, Friedhelm Aubke, F. W. B. Einstein
Publikováno v:
Inorganic Chemistry. 35:82-92
The synthesis of bis(carbonyl)mercury(II) undecafluorodiantimonate(V), [Hg(CO)(2)][Sb(2)F(11)](2), and that of the corresponding mercury(I) salt [Hg(2)(CO)(2)][Sb(2)F(11)](2) are accomplished by the solvolyses of Hg(SO(3)F)(2) or of Hg(2)F(2), treate
Publikováno v:
Organometallics. 13:5113-5121
Publikováno v:
Journal of Organometallic Chemistry. 462:C6-C9
Diphenylacetylene reacts with the pyrolysis product of bis(cyclopentadienyl)-bis( o -fluorophenyl)titanium to afford predominantly one isomer of the expected titanole. The crystal structure of the Cr(CO) 3 derivative 4 of the titanole shows that the
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 47:1185-1188
C 40 H 108 Cl 2 N 8 O 38 cristallise dans I4 avec a=24,702, c=25,768 A, Z=8; affinement jusqu'a R=0,061. La structure contient cinq especes Cu(II) cristallographiquement distinctes. Deux sont impliquees dans un complexe dinucleaire monomerique avec l
Publikováno v:
Inorganic Chemistry. 29:808-814
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 49:470-472
{[(CH 3 ) 3 SiCH 2 ] 2 SnTe} 3 , C 24 H 26 Si 6 Sn 3 Te 3 M r =1262.2, monoclinic, P2 1 /c, a=18.392 (3), b=12.7234 (3), c=22.183 (3) A, β=107.86 (2) o , V=4941 A 3 , Z=4, D x =1.698 g cm -3 , λ(Mo Kα)=0.71069 A, μ=34.14 cm -1 , F(000)=2399.8, T=
Publikováno v:
Inorganic chemistry. 40(23)
A series of coordination polymers containing Cu(II) and [Au(CN)(2)](-) units has been prepared. Most of their structures incorporate attractive gold-gold interactions, thus illustrating that such "aurophilic" interactions can be powerful tools for in
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 47:862-864
[Re(C 2 H 6 O 3 P)(C 10 H 15 )(CO) 2 ] cristallise dans R3 avec a=36,833, b=7,535 A, Z=18; affinement jusqu'a R=0,044. La structure est une pyramide carree coordinee d'ordre 5 avec le cycle Cp centroide occupant l'unique site apique et les groupement