Zobrazeno 1 - 10
of 26
pro vyhledávání: '"F. Kraehenbuehl"'
Publikováno v:
Clay Minerals. 25:499-506
A B S T R A C T: A number of thermodynamic properties were obtained from the determination of adsorption isotherms and enthatpies of immersion for systems with water and Na- and Ca-bentonites. Entropy differences were calculated by combining the enth
The kinetics of the adsorption of dichloromethane vapour by a typical active carbon have been measured at 288 and 323K and for spherical granules of 0.25 and 1.0 mm in diameter. The data have been analysed within the framework of a model for adsorpti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35e8dc56ad6cc950ee0453a517441455
http://doc.rero.ch/record/8305/files/Meunier_Francis_-_A_comparison_of_experimental_and_theoretical_adsorption_kinetics_20071108.pdf
http://doc.rero.ch/record/8305/files/Meunier_Francis_-_A_comparison_of_experimental_and_theoretical_adsorption_kinetics_20071108.pdf
A combination of techniques—mainly immersion calorimetry and adsorption from the vapor phase—provides independent data for the assessment of micropore sizes and their distribution in relation to parameters E0 and n of the Dubinin-Astahhov (D-A) e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd8ab861af81995300c959bb848ee944
http://doc.rero.ch/record/8313/files/St_ckli_Fritz_-_Recent_Developments_in_the_Dubinin_Equation_20071108.pdf
http://doc.rero.ch/record/8313/files/St_ckli_Fritz_-_Recent_Developments_in_the_Dubinin_Equation_20071108.pdf
It is shown that there exists a simple relation between the enthalpy of immersion of pure active carbons into water, and the number of so-called primary adsorption sites a0 derived from the water adsorption isotherm by using the new Dubinin-Serpinsky
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::09b37de185effbccc9ba2fca5d52bbe5
http://doc.rero.ch/record/8298/files/St_ckli_Fritz_-_The_adsorption_of_water_by_active_carbons_20071107.pdf
http://doc.rero.ch/record/8298/files/St_ckli_Fritz_-_The_adsorption_of_water_by_active_carbons_20071107.pdf
Publikováno v:
Clay Minerals. 22:1-9
The adsorption and desorption of water, the layer spacing of the montmorillonite with increasing water content and the heat of immersion with water have been measured for a Na-bentonite and two Ca-bentonites. The bentonite-water system is treated in
The physical and chemical characterization of active carbons, by adsorption and immersion techniques
Publikováno v:
Journal de Chimie Physique. 81:785-790
The combination of organic vapour adsoprtion and immersion calorimetry, both within the framework of Dubinin's theory, leads to information on the micropore system and the external surface area of activated carbons. Immersion into water appears to gi
Autor:
H.F. Stoeckli, F. Kraehenbuehl
Publikováno v:
Carbon. 19:353-356
It is shown that an exact expression can be derived from Dubinin's theory, for the enthalpy of immersion of active carbons. It appears that for a given liquid, the specific enthalpy of immersion is a function of the characteristic energy βE0 of the
Publikováno v:
Carbon. 24:483-488
The combination of gas-solid adsorption experiments with immersion calorimetry of carbons into liquids of increasing molecular dimensions leads to accurate micropore distributions in the range 0.4-0.8 nm. This technique is used to study the developme
Autor:
H.F. Stoeckli, F. Kraehenbuehl
Publikováno v:
Carbon. 22:297-299
Three typical samples of active carbons have been investigated by using immersion calorimetry and adsorption techniques ( t -plot, t F method of Dubinin and direct analysis of the adsorption isotherm before and after prefilling), in order to obtain t