Coincidences, decarboxylation, and electrostatic effects

Autor: F. H. Westheimer

Publikováno v: Tetrahedron. 51:3-20

Electrostatic effects promote the efficiency of acetoacetate decarboxylase and of mandelate racemase by reducing the p K s of their essential lysine residues by about 5 p K units.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e26b676c22dcc40178074b51faecce2a
https://doi.org/10.1016/0040-4020(94)00865-r

Mechanisms Related to Enzyme Catalysis

Autor: F. H. Westheimer

Publikováno v: Advances in Enzymology-and Related Areas of Molecular Biology ISBN: 9780470124888
Advances in Enzymology and Related Areas of Molecular Biology, Volume 24

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::33505f2bcd0ee983b207f489d29d0077
https://doi.org/10.1002/9780470124888.ch9

The Role of Phosphorus in Chemistry and Biochemistry

Autor: F. H. Westheimer

Publikováno v: ACS Symposium Series ISBN: 9780841222137

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e2971343b44089e3ff8bafcdc0ef65a9
https://doi.org/10.1021/bk-1992-0486.ch001

Monomeric metaphosphate anion: reaction with carbonyl groups

Autor: Arnold C. Satterthwait, F. H. Westheimer

Publikováno v: Journal of the American Chemical Society. 103:1177-1180

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c32444439577742b1aa2c0eadc910f29
https://doi.org/10.1021/ja00395a030

Monomeric methyl metaphosphate. 3. Electrophilic aromatic substitution in solution

Autor: Arnold C. Satterthwait, F. H. Westheimer

Publikováno v: Journal of the American Chemical Society. 100:3197-3203

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f220eb56ceb5ec57d9a6da6b3a8f9e52
https://doi.org/10.1021/ja00478a040