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Akademický článek

Co existence of isomeric binuclear tetrahedral Cu(I) complexes and their reaction with [NiCl2(PPh3)2]

Autor: P. Kalaivani, F. Dallemer, R. Prabhakaran

Publikováno v: Chemistry of Inorganic Materials, Vol 3, Iss , Pp 100057- (2024)

Reaction between 2-hydroxy-1-naphthaldehyde thiosemicarbazone and square planar dichloro bis triphenylphosphine Cu(II) resulted in two structurally different binuclear Cu(I) tetrahedral complexes which are co-crystallized together by exhibiting bondi

Externí odkaz: https://doaj.org/article/c6a5b99c9d584a0ca0cf0db7f5bd40dc

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ONO‐Pincer‐Type Coumarin‐Based Copper(II) Metalates: Effect on Alzheimer's Disease Pathologies in Caenorhabditis elegans

Autor: G. Kalaiarasi, S. Dharani, Rathinasabapathi Prabhakaran, F. Dallemer, P. Sundararaj, A. Mohankumar

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2021, 2021 (14), pp.1383-1396. ⟨10.1002/ejic.202100039⟩

International audience

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44bd64e7b1c60fa1273958879241e470
https://doi.org/10.1002/ejic.202100039

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Synthesis of tetranuclear complex of Pd(II) with thiosemicarbazone ligands derived from 2‐quinolone and its catalytic evaluation in Suzuki–Miyaura‐type coupling reactions and alkoxylation of chloroquinolines

Autor: Chennakrishnan Elamathi, S. Dharani, Sundar Nandhini, Rathinasabapathi Prabhakaran, F. Dallemer

Publikováno v: Applied Organometallic Chemistry
Applied Organometallic Chemistry, 2021, 35 (12), ⟨10.1002/aoc.6436⟩

International audience

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b4fdaa708695ec6f1f36914533f4d27
https://hal.science/hal-03662999

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A pseudo trinuclear nickel–sodium complex containing tris(8‐methyl‐2‐oxo‐quinolidineamino ethylamine): Synthesis, spectral characterization, X‐ray crystallography andin vitrobiological evaluations

Autor: D. Anu, Ponmalai Kolandaivel, B. Vijaya Pandiyan, F. Dallemer, P. Naveen, Rathinasabapathi Prabhakaran

Publikováno v: Applied Organometallic Chemistry. 34

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::78535ca4fdf88a9d9cef98bbd6186c29
https://doi.org/10.1002/aoc.5605

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Fluorescent Cu(II) complex as chemosensor for the detection of l-Aspartic acid with high selectivity and sensitivity

Autor: M. Ranjani, P. Kalaivani, Rathinasabapathi Prabhakaran, F. Dallemer, T. Kalpana, S. Selvakumar

Publikováno v: Inorganica Chimica Acta. 530:120683

3-methoxysalicylaldehyde thiosemicarbazone (PL) was used as chemosensor for the detection of various cations (chloride salts). Among them, Cu2+ and Hg2+ ions showed drastic decrease in their fluorescence intensity and colorimetric titrations. Green m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bb883c1c0fb475412d1f532de8e35086
https://doi.org/10.1016/j.ica.2021.120683

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New Ru(II) complexes containing tris(2-pyridylmethyl)amine. Synthesis, structural, CT-DNA/albumin interaction, anti-oxidant and cytotoxicity studies

Autor: Ray J. Butcher, P. Naveen, F. Dallemer, Rathinasabapathi Prabhakaran

Publikováno v: Inorganica Chimica Acta. 471:724-734

Two new Ru(II) complexes containing tris(2-pyridylmethyl)amine was synthesised by reacting [RuCl2 (EPh3)3] E = P, As with TPA.3HClO4 in 1:1 ratio. The new complexes were characterized by various spectroscopic (IR, UV–Vis and NMR) techniques and the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2701b9628a3e41cc81598beff95b562e
https://doi.org/10.1016/j.ica.2017.12.010

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Organometallic ruthenium(II) complexes containing NS donor Schiff bases: Synthesis, structure, electrochemistry, DNA/BSA binding, DNA cleavage, radical scavenging and antibacterial activities

Autor: Rathinasabapathi Prabhakaran, F. Dallemer, P. Kalaivani, G. Devagi

Publikováno v: Journal of Organometallic Chemistry. 854:1-14

Four new cyclopentadienylruthenium(II)-acetophenone-4( N )-substituted thiosemi-carbazone complexes, with the general formula [Ru(ƞ 5 -C 5 H 5 )(H-Aptsc)PPh 3 ].Cl ( 1 ), [Ru(ƞ 5 -C 5 H 5 )(H-Apmtsc)PPh 3 ].Cl ( 2 ), [Ru(ƞ 5 -C 5 H 5 )(H-Ap-etsc)P

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9e2d8bffb1dfd8d97074486c43ff4e76
https://doi.org/10.1016/j.jorganchem.2017.10.036

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Synthesis, characterisation, crystal structures and biological studies of palladium(ii) complexes containing 5-(2-hydroxy-3-methoxy-phenyl)-2,4-dihydro[1,2,4]triazole-3-thione derivatives

Autor: F. Dallemer, A. Shanmugapriya, Rathinasabapathi Prabhakaran

Publikováno v: New Journal of Chemistry. 42:18850-18864

A series of new Pd(II) complexes (1–4) were obtained from the reactions between K2[PdCl4], 3-methoxysalicylaldehyde-4(N)-substituted thiosemicarbazone [H2L1–H2L4] and 1,3-bis(diphenylphosphino)propane [dppp]. All the complexes were characterized

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::02e5c569dd99dfed186f3376c3b2c180
https://doi.org/10.1039/c8nj03714k

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Coumarine based Cu(II) complex as chemosensor for selective detection of l-threonine and l-asparagine

Autor: P. Kalaivani, F. Dallemer, Mathiyazhagan Sindhu, Rathinasabapathi Prabhakaran

Publikováno v: Inorganica Chimica Acta. 526:120525

A new probe [3-AcetCuCl] (where 3-Acet = 3-acetylcoumarine-4(N)-ethylthiosemicarbazone) has been designed and synthesized and it acts a selective and sensitive fluorescent “on–off” chemosensor for l -asparagine and l -threonine. The cytotoxicit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c1b80611f6a16ca0c8ff2e96a6baca1f
https://doi.org/10.1016/j.ica.2021.120525

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