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Publikováno v:
Value in Health. 25:S9
Autor:
Sebastiaan Akerboom, Ireen Schrader, Elisabeth Bouwman, Ilpo Mutikainen, E. Tom Hazenberg, Wen Tian Fu, Sarah F. Verbeek
Publikováno v:
European Journal of Inorganic Chemistry. 2014:4896-4906
Europium(III) and terbium(III) complexes have been prepared using the ligands 2-(4,5-dihydro-1,3-oxazol-2-yl)phenol (HL1) and 2-(4,5-dihydro-1,3-thiazol-2-yl)phenol (HL2) in yields ranging between 74 and 100 %. Metal-to-ligand ratios of 1:3 and 1:4 c
Autor:
F. Verbeek, H. Deelstra
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 73:597-614
The stability constants of some lanthanide-α-hydroxyisobutyrate complex systems have been determined by cation exchange measurements. Fronaeus' method was used to calculate the consecutive formation constants of the terbium and thulium complex syste
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 82:397-403
The complexation between bivalent metal ions and itaconate was investigated potentiometrically at unit ionic strength in NaClO4 at 25.00±0.01°C in the pH region 2-4.5. The complexes ML, ML2, MHL, MHL2 and MH2L2 can be identified and their stability
A Comparative Cation Exchange Study of the Lanthanide Atrolactate and α-Hydroxyisobutyrate Complexes
Autor:
F. Verbeek, H. Thun
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 81:369-378
In order to compare α-hydroxyisobutyrate and atrolactate as complexing eluants for the separation of lanthanide ions on cation exchange resins, the distribution constants for a number of their lanthanide complexes were determined simultaneously at 2
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 72:632-641
The four successive stability constants and their standard deviations have been determined for the α-hydroxy-isobutyrate and lactate complexes of the lanthanide elements and yttrium. A least squares treatment of the experimental data obtained by the
Autor:
F. Verbeek, Z. Eeckhaut
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 67:204-224
The validity of Nernst's law (equation 1), was studied for some reversible oxidation-reduction systems, with oxidation potentials situated at the limit of, or outside the stability range of water. The Ce+4-Ce+3 system in H2S04 0,5 N (E0 = 1,444 V) an
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 90:409-417
Phase diagrams were constructed from phase equilibrium calculations for the quaternary system Ca(OH)2-Sr (OH)2-H3PO4-H2O and for the system Ca(OH)2-Sr(OH)2-H3PO4-HX(BOH)-H20 at 25°. On the basis of these diagrams the stability field of solid solutio