Thermally Ultra-Robust S = ½ Tetrazolinyl Radicals: Synthesis, Electronic Structure, Magnetism, and Nanoneedle Assemblies on Silicon Surface

Autor: Zhimin Yang, Maren Pink, Ewa Malgorzata Nowik-Boltyk, Shutian Lu, Tobias Junghoefer, Suchada Rajca, Stefan Stoll, Maria Benedetta Casu, Andrzej Rajca

Open-shell organic molecules, including S = ½ radicals, may provide enhanced properties for several emerging technologies, however, relatively few synthesized to date possess robust thermal stability and processability. We report synthesis of S = ½

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e1efc5ce7f4d82ef0c9dc6ad54b06cac
https://doi.org/10.26434/chemrxiv-2023-7njqc

Exploiting the versatile alkyne-based chemistry for expanding the applications of a stable triphenylmethyl organic radical on surfaces

Autor: Bruno Fabre, Núria Crivillers, Tobias Junghoefer, Erika Giangrisostomi, Ruslan Ovsyannikov, Francesc Bejarano, Maria Benedetta Casu, Concepció Rovira, Marta Mas-Torrent, Diego Gutiérrez, Ewa Malgorzata Nowik-Boltyk, J. Alejandro de Sousa, Yann R. Leroux, Jaume Veciana

Publikováno v: Chemical Science
Chemical Science, The Royal Society of Chemistry, 2020, 11 (2), pp.516-524. ⟨10.1039/c9sc04499j⟩
Digital.CSIC. Repositorio Institucional del CSIC
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Chemical Science, 2020, 11 (2), pp.516-524. ⟨10.1039/c9sc04499j⟩

The incorporation of terminal alkynes into the chemical structure of persistent organic perchlorotriphenylmethyl (PTM) radicals provides new chemical tools to expand their potential applications. In this work, this is demonstrated by the chemical fun

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e8c203907eea6c20524d8214e450ed12
http://hdl.handle.net/10261/211999