Zobrazeno 1 - 10
of 112
pro vyhledávání: '"Evgenii T Denisov"'
Autor:
Evgenii T Denisov, T. G. Denisova
Publikováno v:
Kinetics and Catalysis. 60:1-7
Experimental data on the reaction of hydrogen atom abstraction from hydrocarbons, halogenated alkanes, and oxygen-containing compounds by oxygen atoms (50 reactions) are analyzed using the intersecting parabolas model. The influence of five factors o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6bbc0f8b8210686c2845e16fbd20431f
https://doi.org/10.1134/s0023158419010038
https://doi.org/10.1134/s0023158419010038
Publikováno v:
Russian Journal of Physical Chemistry A. 92:853-861
Reactions of the type X• + HCR2CH2NO2 → XH + R2C=CH2 + N•O2 are exothermic, due to the breaking of weak C–N bonds and the formation of energy-intensive C=C bonds. Quantum chemistry calculations of the transition state using the reactions of E
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f5c0f7e6cf5a4deaaa4f8d823fbf5269
https://doi.org/10.1134/s0036024418050072
https://doi.org/10.1134/s0036024418050072
Autor:
Evgenii T Denisov, T. G. Denisova
Publikováno v:
Kinetics and Catalysis. 59:1-5
The experimental data on the reactions of iodine atoms with olefins, alkyl halides, and oxygencontaining compounds (20 reactions) are analyzed under the model of intersecting parabolas (MIPs). The effect of the following factors on the activation ene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d72b983f2787fbcb2371dcdb9d945e1c
https://doi.org/10.1134/s0023158418010044
https://doi.org/10.1134/s0023158418010044
Publikováno v:
Kinetics and Catalysis. 58:679-687
The reactions X• + HCR2ONO2 → XH + R2C=O + •NO2 are very exothermic due to the cleavage of the weak N−O bond and the formation of the energy-intensive C=O bond. The quantum chemical calculation of the transition state of these reactions for X
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bab751dc688ace23c6a60f128b65575c
https://doi.org/10.1134/s0023158417050044
https://doi.org/10.1134/s0023158417050044
Autor:
Evgenii T Denisov, T. S. Pokidova
Publikováno v:
Russian Journal of Physical Chemistry A. 91:1373-1379
Experimental results on the coordinated molecular decomposition of RF fluoroalkanes to olefin and HF are analyzed using the model of intersecting parabolas (IPM). The kinetic parameters are calculated to allow estimates of the activation energy (E) a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9f3ad9965fa3e1960db6d923d3daf17b
https://doi.org/10.1134/s0036024417080271
https://doi.org/10.1134/s0036024417080271
Autor:
Evgenii T Denisov, T. G. Denisova
Publikováno v:
Kinetics and Catalysis. 58:349-354
Experimental data concerning reactions of the bromine atoms with haloalkanes and carbonyl compounds (25 reactions) have been analyzed within the intersecting parabolas model. The following factors have an effect on the activation energy of these reac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c37ce699f549a89e1f0438492bdbc6b
https://doi.org/10.1134/s0023158417040061
https://doi.org/10.1134/s0023158417040061
Autor:
Evgenii T Denisov, T. G. Denisova
Publikováno v:
Kinetics and Catalysis. 58:219-226
Experimental kinetic data on reactions of the chlorine atom with halogenated derivatives of methane and ethane (37 reactions) have been analyzed by the intersecting-parabolas method. The following five factors have an effect on the activation energy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b4d3d5f237f5b9a80007bcfd49abf561
https://doi.org/10.1134/s0023158417030041
https://doi.org/10.1134/s0023158417030041
Autor:
Evgenii T Denisov, T. G. Denisova
Publikováno v:
Kinetics and Catalysis. 58:15-23
The O−H bond dissociation energy (D O−H) has been determined for eight alkylseleno-substituted phenols, one alkyltelluro-substituted phenol, and one alkyltelluro-substituted pyridinol. D O−H has been estimated by the intersecting-parabolas meth
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e10ca502913b3fa6a6beeb2cc31a51c0
https://doi.org/10.1134/s0023158417010013
https://doi.org/10.1134/s0023158417010013
Autor:
Evgenii T Denisov
Publikováno v:
Kinetics and Catalysis. 57:750-757
The activation energy and rate constant of the reaction between the nitroxyl radical and N-alkoxyamine as a concerted abstraction–fragmentation reaction have been calculated using the intersecting parabolas model. This reaction proceeds fairly rapi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1fccd554fe02e6c388087d3adade7f09
https://doi.org/10.1134/s0023158416060057
https://doi.org/10.1134/s0023158416060057
Autor:
T. G. Denisova, Evgenii T Denisov
Publikováno v:
Kinetics and Catalysis. 57:723-730
The O−H bond dissociation energy (DO−H) has been estimated for 20 substituted 3-pyridinols and a substituted 3-pyrimidinol from experimental kinetic data by the intersecting parabolas method using α-tocopherol and 4-methoxyphenol as reference co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d9e187eb224976dd0913d86be531a79c
https://doi.org/10.1134/s0023158416050086
https://doi.org/10.1134/s0023158416050086