Zobrazeno 1 - 10 of 234 pro vyhledávání: '"Eva Rentschler"'
1
Akademický článek
Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides
Autor: Stefan Repp, Moritz Remmers, Alexandra Stefanie Jessica Rein, Dieter Sorsche, Dandan Gao, Montaha Anjass, Mihail Mondeshki, Luca M. Carrella, Eva Rentschler, Carsten Streb
Publikováno v: Nature Communications, Vol 14, Iss 1, Pp 1-7 (2023)
Abstract The introduction of metal sites into molecular metal oxides, so-called polyoxometalates, is key for tuning their structure and reactivity. The complex mechanisms which govern metal-functionalization of polyoxometalates are still poorly under
Externí odkaz: https://doaj.org/article/a973178ab9364286b156be0b600901cf
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2
Akademický článek
Luminescent Cadmium(II)-Based 12-MC-4 Metallacrown Complex with 2-Methylmercaptobenzohydroxamic Acid Ligand
Autor: Sriram Sundaresan, Christoph Gamer, Mortiz J. Förster, Luca M. Carrella, Eva Rentschler
Publikováno v: Inorganics, Vol 11, Iss 9, p 362 (2023)
We reported herein the synthesis, structure determination and emission properties of a cubic molecular Cd(II) coordination cluster whose faces are composed of 12-MC-4 metallacrown units built up from Cd2+ and 2-methylmercaptobenzohydroxamic acid (Lmm
Externí odkaz: https://doaj.org/article/32dcb975555e4f76ad21cc60b901a812
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3
Akademický článek
Triggering of Valence Tautomeric Transitions in Dioxolene-Based Cobalt Complexes Influenced by Ligand Substituents, Co-ligands, and Anions
Autor: Sriram Sundaresan, Marcel Diehl, Luca M. Carrella, Eva Rentschler
Publikováno v: Magnetochemistry, Vol 8, Iss 9, p 109 (2022)
We report the multistep synthesis of the 1,1′-(piperazine-1,4-diyl)bis(N,N-bis(pyridin-2-ylmethyl)methanamine)(Ltpbap) octadentate ligand, which, in combination with the known 3,5-di-tert-butylcatechol (3,5-dbcat), allowed the preparation of two di
Externí odkaz: https://doaj.org/article/f50e8f12c8ff4e5db0d0e10415d309fb
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5
Akademický článek
Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes
Autor: Sriram Sundaresan, Julian Eppelsheimer, Luca M. Carrella, Eva Rentschler
Publikováno v: Crystals, Vol 12, Iss 3, p 404 (2022)
Novel synthesis of 2,5-bis[(1,3-thiazol-2-ylmethyl)amino]methyl-1,3,4-oxadiazole (LThiazole) is reported, along with the preparation of three new dinuclear Fe(II) complexes with different counterions [FeII2(μ2-LThiazole)2](BF4)4·2CH3CN (1), [FeII2(
Externí odkaz: https://doaj.org/article/e245ca49fdf64fada3ec39ff8efbbced
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6
Structural insight into halide-coordinated [Fe4S4XnY4−n]2− clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy
Autor: Andreas O. Schüren, Benjamin M. Ridgway, Florencia Di Salvo, Luca M. Carella, Verena K. Gramm, Elisa Metzger, Fabio Doctorovich, Eva Rentschler, Volker Schünemann, Uwe Ruschewitz, Axel Klein
Publikováno v: Dalton Transactions. 52:1277-1290
Single crystal XRD at 298 and 173 K, magnetic measurements from 2 to 300 K and 57Fe Mössbauer spectroscopy of (BTMA)2[Fe4S4X2Y2] (X, Y = Cl, Br, or I) showed that the variation of X and Y had no effect on the delocalisation of Fe2.5+/Fe2.5+ in the c
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7d1a430fd755df563d1ba29fe9694466
https://doi.org/10.1039/d2dt03203a
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7
Akademický článek
Spin-Crossover in Iron(II) Complexes of N,N′-Disubstituted 2,6-Bis(Pyrazol-3-yl)Pyridines: An Effect of a Distal Substituent in the 2,6-Dibromophenyl Group
Autor: Igor A. Nikovskiy, Alexander V. Polezhaev, Valentin V. Novikov, Dmitry Yu. Aleshin, Rinat R. Aysin, Elizaveta K. Melnikova, Luca M. Carrella, Eva Rentschler, Yulia V. Nelyubina
Publikováno v: Crystals, Vol 11, Iss 8, p 922 (2021)
A series of new bis(pyrazol-3-yl)pyridines (LR) N,N′-disubstituted by 4-functionalized 2,6-dibromophenyl groups have been synthesized to study the effect of a distal substituent on the spin-crossover (SCO) behaviour of the iron(II) complexes [Fe(LR
Externí odkaz: https://doaj.org/article/c03d60e62cb74dc0a78b045da00ad8b6
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10
Akademický článek
2D Layer Arrangement of Solely [HS-HS] or [LS-LS] Molecules in the [HS-LS] State of a Dinuclear Fe(II) Spin Crossover Complex
Autor: Fabian Fürmeyer, Luca M. Carrella, Eva Rentschler
Publikováno v: Crystals, Vol 10, Iss 6, p 448 (2020)
Herein we report the synthesis and characterization of three new dinuclear iron(II) complexes [FeII2(I4MTD)2](F3CSO3)4 (C1), [FeII2(I4MTD)2](ClO4)4 (C2) and [FeII2(I4MTD)2](BF4)4 (C3) based on the novel ligand (I4MTD = 2,5-bis{[(1H-imidazol-4-ylmethy
Externí odkaz: https://doaj.org/article/1b33fbe2d2b84213aa8e6b045a804800
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