Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Eugene G. Yang"'
Autor:
Subramanian G. Gramani, Ravi K. Sriramula, Karthik Sekar, Praveena Battu, Eugene G. Yang, Martin J. Lear, Aïcha Kopecky
A concise, (Z)-selective ring-closing metathesis (RCM) route to the 14-membered carbocycle of bielschowskysin is detailed, using nat-urally occurring chiral starting materials. Unproductive RCM substrates were attributed to alkyne chelation of the ru
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7753760600f754a52c6e83ef038d9a7
Publikováno v:
Tetrahedron Letters. 54:4406-4408
By judicious choice of a conformationally constraining unit to predispose cyclisation to a 15-membered ring, we present a straightforward strategy to a cembranolide precursor of bielschowskysin by the Sonogashira coupling of two readily prepared frag