Zobrazeno 1 - 10
of 91
pro vyhledávání: '"Eugene E. Petersen"'
Publikováno v:
Journal of Applied Physics. 72:3289-3293
Part I of this paper presented a generalized model of heat effects operative during surface reactions. The enhancement in reaction rate due to autothermic effects was analyzed as a function of activation energy, bulk temperature, and a parameter term
Publikováno v:
Journal of Applied Physics. 72:3282-3288
Many important classes of surface reactions exhibit both high heats of reaction and large, positive activation energies. In addition, many surface reactions often occur in thermally isolated environments. As a result, significant autothermic effects
Publikováno v:
AIChE Journal. 36:1562-1568
Xenon-129 NMR is used to probe macroscopic distributions of aromatic molecules adsorbed in a packed bed of 1-μm NaY zeolite particles. Relative rates of guest transport through the intracrystalline (micro) and intercrystalline (macro) pores play a u
Autor:
Eugene E. Petersen, Eduardo E. Wolf
Publikováno v:
Chemical Engineering Science. 29:1500-1503
Autor:
Eugene E. Petersen, Michael A. Pacheco
Publikováno v:
Journal of Catalysis. 96:499-506
A comparative study of the activity and selectivity maintenance of reforming catalysts is presented. The stability of the catalysts is not significantly affected by varying the drying temperature but it is very definitely affected by sulfur pretreatm
Publikováno v:
Journal of Catalysis. 34:294-306
An apparatus was constructed to study catalytic reactions on one or more platinum single crystals in situ both at 1 atm total pressure and in high vacuum (10/sup -4/ to 10/sup -8/ torr). The main feature of the design is a novel movable bellows-cup m
Autor:
Bruce H. Isaacs, Eugene E. Petersen
Publikováno v:
Journal of Catalysis. 85:8-15
Surface area measurement has been used to examine the effects of catalyst pretreatment on reduced Pt/Re/Al2O3 catalysts. The results indicate significant alloy formation in reduced Pt/Re/ Al2O3 for all drying temperatures of 500 °C or less. While th
Autor:
Eugene E. Petersen, Eduardo E. Wolf
Publikováno v:
Chemical Engineering Science. 32:493-497
The single-pellet diffusion reactor has proven to be a particularly useful tool to diagnose the mechanism of catalyst poisoning. Previous work was done with main reactions of first, second and 1/2 order and behavior was found to be similar for reacti
Autor:
Michael A. Pacheco, Eugene E. Petersen
Publikováno v:
Journal of Catalysis. 96:507-516
An investigation of the reaction kinetics of methylcyclohexane (MCH) dehydrogenation over a sulfided Pt + Re Al 2 O 3 reforming catalyst is presented. The main reaction kinetics cannot be modeled completely with simple Langmuir-Hinshelwood techniques
Publikováno v:
Journal of Catalysis. 117:52-70
A transport model is presented for the coimpregnation of a metal salt and an acid into a porous oxide where equilibrium adsorption is controlled by hydrolysis of surface hydroxyl groups and ion binding on these groups. The transport and adsorption eq