Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Esther M. S. Pérez"'
Publikováno v:
Molecules, Vol 29, Iss 17, p 4131 (2024)
A curious and noticeable structural feature in Schiff bases from 2-aminoaldoses is the fact that imino tautomers arranged equatorially in the most stable ring conformation exhibit a counterintuitive reverse anomeric effect (RAE) in the mutarotational
Externí odkaz:
https://doaj.org/article/6971830141924c8fabe67d63dba1cb65
Autor:
Pedro Cintas, Martin Avalos, Mark E. Light, R. Fernando Martínez, Vicenta Rastrojo, José L. Jiménez, Juan C. Palacios, Reyes Babiano, Esther M. S. Pérez
Publikováno v:
Tetrahedron. 67:2025-2034
Schiff bases derived from 2-hydroxy-1-naphthaldehyde, or 1-hydroxy-2-naphthaldehyde, and different saturated N-aminoheterocycles have been prepared. Their structures have been elucidated in both solution and the solid state, including unequivocal X-r
Autor:
Esther M. S. Pérez, Martin Avalos, Pedro Cintas, Mark E. Light, Reyes Babiano, Juan C. Palacios, R. Fernando Martínez, José L. Jiménez
Publikováno v:
European Journal of Organic Chemistry. 2010:6224-6232
This paper describes the synthesis and structural elucidation of 1,3-oxazolidines derived from tris(hydroxymethyl)aminomethane (TRIS) and pyridine-based aldehydes. Divergent results were obtained with other formylpyridines, such aspyridoxal, in which
Autor:
José L. Jiménez, Pedro Cintas, R. Fernando Martínez, Juan C. Palacios, Martin Avalos, Mark E. Light, Reyes Babiano, Esther M. S. Pérez
Publikováno v:
European Journal of Organic Chemistry. 2010:5263-5273
A series of oxazolidines derived from tris(hydroxymethyl)aminomethane (TRIS; 1), have been prepared efficiently. Geometries optimized at the B3LYP/6-31G* level of theory, along with the crystal data of compounds 9 and 12 and NOESY correlations, point
Autor:
Esther M. S. Pérez, Mark E. Light, José L. Jiménez, Ana Sancho, Pedro Cintas, Reyes Babiano, Juan C. Palacios, M. Avalos
Publikováno v:
Carbohydrate Research. 345:23-32
Despite the comprehensive literature and enormous versatility of chiral imines derived from aminosugars and aldehydes, the corresponding counterparts generated from ketones remain an underestimated research subject. Filling in the gap, this manuscrip
Autor:
R. Fernando Martínez, Esther M. S. Pérez, Pedro Cintas, Reyes Babiano, Martin Avalos, Juan C. Palacios, Mark E. Light, José L. Jiménez
Publikováno v:
Tetrahedron. 64:6377-6386
A one-pot procedure for preparing chiral 1,3-oxazolidines derived from N-methyl-d-glucamine and aryl aldehydes is described. It has been carried out by using readily available reagents and operationally simple conditions allowing the preparation of t
Autor:
Pedro Cintas, Esther M. S. Pérez, José L. Jiménez, Martin Avalos, Mark E. Light, Juan C. Palacios, Reyes Babiano
Publikováno v:
The Journal of Organic Chemistry. 73:661-672
A series of chiral imines derived from 1-amino-1-deoxyalditols such as d-glucamine, a rather unexplored raw material from the chiral pool, have been serendipitiously transformed into a novel family of N-acetyl-1,3-oxazolidines by means of an unexpect
Synthesis of Sugar Isocyanates and Their Application to the Formation of Ureido-Linked Disaccharides
Autor:
Juan C. Palacios, Martin Avalos, Mark E. Light, Reyes Babiano, Esther M. S. Pérez, Pedro Cintas, Michael B. Hursthouse, José L. Jiménez
Publikováno v:
European Journal of Organic Chemistry. 2006:657-671
The present work describes a facile and practical route to carbohydrate-based isocyanates, a reactive and appealing family of chiral heterocumulenes, wich can be easily converted into disaccharides and pseudodisaccharides interconnected by urea moiet
Autor:
Esther M. S. Pérez, Juan C. Palacios, José L. Jiménez, Reyes Babiano, R. Fernando Martínez, Martin Avalos, Pedro Cintas
Publikováno v:
Organic & Biomolecular Chemistry. 9:3279
The conformational population of Z and E isomers of the amide bond in N-acetyl oxazolidines is dictated by the electronic nature of the vicinal aryl ring. Experimental and theoretical data support a rationale based on a strong and stereodirecting cha
Autor:
Martín Ávalos, Reyes Babiano, Pedro Cintas, Michael B. Hursthouse, José L. Jiménez, Mark E. Light, Juan C. Palacios, Esther M. S. Pérez
Publikováno v:
European Journal of Organic Chemistry; Jan2006, Vol. 2006 Issue 3, p657-671, 15p