Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Estelle L. Lebeau"'
Autor:
Estelle L Lebeau
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 212:83-89
The Os(III) complexes [OsIII(tpy)(bpy)(py)]3+ and [OsIII(bpy)3]3+ (bpy: 2,2′-bipyridine, py: pyridine, tpy: 2,2′,2′′-terpyridine) are unstable toward self-reduction in alkaline solution. Product analysis performed by using UV-Vis spectroscopy
Autor:
David W. Thompson, Donald V. Scaltrito, Arnold L. Rheingold, Gerald J. Meyer, Reza A. Ghiladi, Ryan M. Kretzer, Kin Chung Lam, Estelle L. Lebeau, Kenneth D. Karlin
Publikováno v:
Inorganic Chemistry. 42:5211-5218
We present here the synthesis, characterization, and flash photolysis study of [(F(8)TPP)Fe(II)(CO)(THF)] (1) [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]. Complex 1 crystallizes from THF/heptane solvent system as a tris-THF solvate, [(F(
Publikováno v:
Journal of the American Chemical Society. 123:10535-10544
The kinetics of electron transfer for the reactions cis-[Ru(IV)(bpy)2(py)(O)]2+ + H+ + [Os(II)(bpy)3]2+==cis-[Ru(III)(bpy)2(py)(OH)]2+ + [Os(III)(bpy)3]3+ and cis-[Ru(III)(bpy)2(py)(OH)]2+ + H+ + [Os(II)(bpy)3]2+==cis-[Ru(II)(bpy)2(py)(H2O)]2+ + [Os(
Publikováno v:
Inorganic Chemistry. 37:6476-6484
The complex [(tpy)(C(2)O(4))Ru(III)ORu(III)(C(2)O(4))(tpy)].8H(2)O (1.8H(2)O) (tpy is 2,2':6',2"-terpyridine) has been prepared and characterized by X-ray crystallography and FTIR, resonance Raman, and (1)H NMR spectroscopies. From the results of the
Autor:
Hershel Jude, Dana M. Dattelbaum, Darla Graff Thompson, Luis M. Baraldo, Javier J. Concepcion, Joe D. Thompson, Jonah W. Jurss, Reginaldo C. Rocha, Estelle L. Lebeau, Kristin M. Omberg, Jennifer M. Butler, Brooks J. Hornstein, Joseph L. Templeton, Jon R. Schoonover, Thomas J. Meyer
Publikováno v:
Inorganic chemistry. 51(3)
The first designed molecular catalyst for water oxidation is the "blue dimer", cis,cis-[(bpy) 2(H 2O)Ru IIIORu III(OH 2)(bpy) 2] 4+. Although there is experimental evidence for extensive electronic coupling across the μ-oxo bridge, results of earlie
Publikováno v:
Journal of the American Chemical Society. 116:4858-4865
A multidentate ligand is bonded to cyclodextrins by the reaction of diethylenetriaminepentaacetic dianhydride with 6-mono- and 2-mono(ethylenediamine) derivatives of cyclodextrin. Adding Dy(III) to the cyclodextrin derivatives enhances the enantiomer
Publikováno v:
Inorganic chemistry. 42(9)
Carbon monoxide readily binds to heme and copper proteins, acting as a competitive inhibitor of dioxygen. As such, CO serves as a probe of protein metal active sites. In our ongoing efforts to mimic the active site of cytochrome c oxidase, reactivity
Autor:
Thomas J. Meyer, Estelle L. Lebeau
Publikováno v:
Inorganic chemistry. 38(9)
The kinetics and mechanism of reduction of trans-[Ru(VI)(tpy)(O)(2)(L)](2+) (L is H(2)O or CH(3)CN; tpy is 2,2':6',2' '-terpyridine) by benzyl alcohol have been studied in water and acetonitrile. The reactions are first order in alcohol and complex i