Absence of intermediates in the BINOL-derived mg(ii)/phosphate-catalyzed desymmetrizative ring expansion of 1-Vinylcyclobutanols

Autor: Estefania Capel, Marta Rodríguez-Rodríguez, Uxue Uria, Manuel Pedron, Tomas Tejero, Jose L. Vicario, Pedro Merino

Publikováno v: Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname
Addi. Archivo Digital para la Docencia y la Investigación
The Journal of Organic Chemistry
Digital.CSIC. Repositorio Institucional del CSIC

The catalyzed desymmetrizative ring expansion of alkenylcyclobutanols promoted by halofunctionalization of the alkene moiety with N-bromosuccinimide has been experimentally and computationally studied. The reaction yields highly enantioenriched cyclo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f0a4a3fdee7d2429624f4e6e6489be7
http://zaguan.unizar.es/record/112144