Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Errol Fernandes"'
Publikováno v:
Journal of Environmental Quality. 31:437-444
Organic pollutants are degraded in soil and simultaneously non-extractable residues are formed. However, proof is lacking that this fixation has a detoxifying effect. We investigated the transformation and binding of 2,4,6-trinitrotoluene (TNT) with
Publikováno v:
Environmental Science & Technology. 33:4448-4456
Evidence is presented for the covalent binding of biologically reduced metabolites of 2,4,6-15N3-trinitrotoluene (TNT) to different soil fractions (humic acids, fulvic acids, and humin) using liquid 15N NMR spectroscopy. A silylation procedure was us
The Effects of Substituents on the Degenerate Cope Rearrangement of Semibullvalenes and Barbaralanes
Publikováno v:
European Journal of Organic Chemistry. 1998:2209-2227
The activation parameters [ΔG# (200 K), ΔH#, and ΔS#] for the degenerate Cope rearrangements of barbaralane (1a) and several semibullvalenes (3a, 7a, 8a), and for those of a number of their 3,7- and 2,6-disubstituted derivatives, have been determi
Publikováno v:
The Journal of Organic Chemistry. 63:3302-3309
The synthesis and study of a novel bisannelated semibullvalene that is calculated to be a neutral homoaromatic ground state molecule is presented. Through variable-temperature X-ray, 13C solution-p...
Publikováno v:
Environmental Science & Technology. 31:2991-2997
Soil-bound residues of the fungicide cyprodinil (4-cyclopropyl-6-methyl-2-phenylaminopyrimidine), which was labeled with 13C and 14C either in the phenyl ring or the pyrimidyl ring, were analyzed by a silylation procedure and 13C-NMR spectroscopy. Af
Publikováno v:
Environmental Science & Technology. 31:2392-2398
To elucidate the binding mechanism of the herbicide bentazon (3-isopropyl-1H-2,1,3-benzothiadiazine-4(3H)-one 2,2-dioxide) with humic monomers in the presence of an oxidative enzyme, the reaction of bentazon with catechol, caffeic acid, protocatechui
Publikováno v:
Journal of Agricultural and Food Chemistry. 45:514-520
The fungicide cyprodinil [4-cyclopropyl-6-methyl-2-(phenylamino)pyrimidine] labeled with 14C in either the phenyl or the pyrimidyl ring was incubated with four different soils under various conditions to evaluate the formation of bound residues and t
Publikováno v:
The Journal of Physical Chemistry. 98:8498-8506
Publikováno v:
ChemInform. 30
The activation parameters [ΔG# (200 K), ΔH#, and ΔS#] for the degenerate Cope rearrangements of barbaralane (1a) and several semibullvalenes (3a, 7a, 8a), and for those of a number of their 3,7- and 2,6-disubstituted derivatives, have been determi
Autor:
Kamlesh Chauhan, and Vijay R. Gadgil, Errol Fernandes, M. Bilayet Hossain, Lloyd M. Jackman and, Richard V. Williams, Dick van der Helm and
Publikováno v:
Journal of the American Chemical Society. 118:4208-4209