Zobrazeno 1 - 10
of 62
pro vyhledávání: '"Ernst D. von Meerwall"'
Publikováno v:
The journal of physical chemistry. B. 122(50)
Many natural and synthetic polymers and particles have a rodlike shape, leading to important and intriguing solution behavior, such as high intrinsic viscosities and liquid crystalline phases. Much of what is known about suspensions of rods has been
Autor:
Emmanuel P. Giannelis, Richard A. Vaia, Peter A. Mirau, Hilmar Koerner, Ernst D. von Meerwall, Michael L. Jespersen, Nikhil J. Fernandes
Publikováno v:
Macromolecules. 46:9669-9675
Nanoscale ionic materials (NIMs) are organic–inorganic hybrids prepared from ionically functionalized nanoparticles (NP) neutralized by oligomeric polymer counterions. NIMs are designed to behave as liquids under ambient conditions in the absence o
Publikováno v:
Macromolecules. 42:8864-8869
We have performed dynamic Monte Carlo (MC) simulations and pulsed-gradient diffusion (D) experiments to study the effect of stereochemical composition on diffusion in linear polypropylene (PP) melt...
Publikováno v:
Rubber Chemistry and Technology. 80:854-872
In an effort to understand the effect of ultrasound on the devulcanization of gum and filled isoprene rubber vulcanizates, solid state NMR 1H transverse relaxation (T2) was employed to analyze rubber molecular mobility. The T2 relaxation decay of the
Publikováno v:
Macromolecules. 40:3970-3976
We have used the 1H pulsed-gradient NMR method to augment our earlier diffusion measurements in n-alkane and polyethylene (PE) melts and blends with measurements in 12 additional melts and in three series of blends at T = 150 °C across the full conc
Publikováno v:
Macromolecules. 40:2002-2007
We have performed pulsed-gradient NMR diffusion (D) measurements of five n-alkanes (24, 28, 36, 44, and 60 carbons) in a polyethylene (PE) host (molecular weight M = 33 kDa) as a function of concentration c (2−10 wt %) at 180 °C. Monte Carlo simul
Publikováno v:
Macromolecules. 40:1504-1511
We conduct a comprehensive study of the effect of stereochemistry on the diffusion of isotactic, atactic, and syndiotactic polypropylene (PP), with dynamical Monte Carlo. We simulate realistic two-bead Monte Carlo moves on a stereochemistry-dependent
Publikováno v:
Macromolecules. 40:959-966
The dynamics of bidisperse (1K/4.5K) polyethylene (PE) melts in the Rouse-reptation transitional region is studied using a newly designed dynamic Monte Carlo algorithm on a high-coordination (2nnd) lattice. The internal relaxation modes fit the KWW r
Autor:
J. C. Parr, Joseph L Massey, Chang Kook Hong, Ernst D. von Meerwall, Todd A. Wagler, Avraam I. Isayev
Publikováno v:
Polymer International. 56:860-869
13C NMR solids spectroscopy and transverse relaxation, and 1H relaxation and pulsed-gradient spin-echo self-diffusion measurements at 70 °C were used to study molecular and segmental mobilities in natural rubber before and after sulfur crosslinking,
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 44:2556-2571
A detailed comparison is made between the experiment, prior simulations by other groups, and our simulation based on a newly designed dynamic Monte Carlo algorithm, on the dynamics of polyethylene (PE) melts. The new algorithm, namely, noncross rando