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Publikováno v:
Tetrahedron Letters. 40:9201-9204
A simple water soluble diselenide derivative 1 shows radical scavenger properties towards alkyl and hydroxyl radicals (k3 (0°C)=6.8×108 M−1 s−1) in Fenton-type chemistry. The reaction rate between produceded alkyl radicals 2 and the diselenide
Publikováno v:
Tetrahedron. 54:15087-15096
In the FeIII-FeV manifold the formation of the iron-carbon bond was found to be very fast, but the evolution to give ketone was slow at −20 °C and −40 °C. However, the efficiency at the latter temperature was good. The iron-carbon bond can be c