Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Eric M. Tippmann"'
Publikováno v:
PLoS ONE, Vol 10, Iss 5, p e0127504 (2015)
Expanded genetic code approaches are a powerful means to add new and useful chemistry to proteins at defined residues positions. One such use is the introduction of non-biological reactive chemical handles for site-specific biocompatible orthogonal c
Externí odkaz:
https://doaj.org/article/71c96f16787f478588106260ad200f47
Publikováno v:
Photochemicalphotobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology. 18(1)
A photochemically chemically active noncanonical amino acid para-azido-L-phenylalanine widely used in biology was found to be metabolized by Saccharomyces cerevisiae. Contrary to multiple reports, the azide moiety is not reduced to the corresponding
Autor:
Samuel C. Reddington, Pierre J. Rizkallah, Peter D. Watson, Rachel Pearson, Eric M. Tippmann, D. Dafydd Jones
Publikováno v:
Angewandte Chemie. 125:6090-6093
Autor:
Sen Jason Li, Michael J. Yurkovich, Matthew S. Platz, Ryan C. Shea, Sarah M. Mandell, Michael A. Watkins, Hilkka I. Kenttämaa, Penggao Duan, Eric M. Tippmann
Publikováno v:
International Journal of Mass Spectrometry. 287:16-20
The reactivity of two metallated nitrenium ions toward various substrates was examined in the gas phase. The nitrenium ions were generated by a reaction of benzoyl azide with laser-ablated Mg + or Cu + in a Fourier transform ion cyclotron resonance m
Publikováno v:
The Journal of Physical Chemistry A. 108:1033-1041
Singlet fluorocarbenes substituted with diphenylphosphanyl, phenylsulfanyl, and trimethylsilyl groups were generated upon photolysis of the corresponding tricyclo[4.3.1.0]decadiene precursors 1a−c....
Publikováno v:
Organic Letters. 5:4919-4922
Carbomethoxyfluorocarbene was studied in solution by laser flash photolysis with UV-vis and infrared detection. In contrast to expectations, carbomethoxyfluorocarbene is more reactive than carbomethoxychlorocarbene. [structure: see text]
Autor:
Matthew S. Platz, Eric M. Tippmann
Publikováno v:
The Journal of Physical Chemistry A. 107:8547-8551
10-exo-Fluoro-10‘-endo-chlorotricylco[4.3.1.01,6]decadiene-2,4 (1) was synthesized. Continuous photolysis of 1 (300 nm) generates chlorofluorocarbene 2, which can be intercepted with tetramethylethylene (TME) to form the expected cyclopropane 3. La
Autor:
Brian T. Hill, Eric M. Tippmann, Matthew S. Platz, Zhendong Zhu, Eunju Lee Tae, Igor Likhotvorik
Publikováno v:
Journal of the American Chemical Society. 123:6061-6068
Photolysis (254 nm) of methyl 8-chloro-3a,7a-methanoindan-8-carboxylate (5) in argon at 14 K produces carbomethoxychlorocarbene (6) as a persistent species. The IR and UV-vis spectra of the carbene were recorded and analyzed with the aid of density f
Publikováno v:
Tetrahedron Letters. 42:3049-3051
A new non-nitrogenous precursor of dimethylcarbene has been synthesized. Photolysis of 10,10′-dimethyltricyclo[4.3.1.0 1,6 ]deca-2,4-diene in solution with 254 nm light produces dimethylcarbene. Previously unknown intermolecular reactions of dimeth
Publikováno v:
Organic letters. 6(5)
A photosensitive precursor (1) to phenylsulfanylcarbene 2 has been synthesized. Laser flash photolysis (308 nm) of 1 and chemical trapping studies of 2 are reported. [structure: see text]