Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Eric J. Tisdale"'
Publikováno v:
Organic Letters. 5:1491-1494
An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the implementation of a biomimetic tandem Claisen/Diels-Alder reaction that produced the desired tricyclic scaffold as a single isom
Publikováno v:
Organic Letters. 4:909-912
[reaction: see text] Two different routes to the tricyclic core of Garcinia-derived natural products are described. The first approach is based on a tandem Claisen/Diels-Alder rearrangement and delivers the desired lactone 14. The second approach, em
A unified synthetic strategy toward caged Garcinia natural products has been designed and implemented. Central to the strategy is a tandem Claisen/Diels–Alder/Claisen rearrangement of a suitably substituted xanthone precursor to form forbesione (1a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::47ce88e27a143a53a92aa1856eb30cf2
https://europepmc.org/articles/PMC514429/
https://europepmc.org/articles/PMC514429/
Publikováno v:
ChemInform. 35
Publikováno v:
Organicbiomolecular chemistry. 1(24)
A concise synthesis of forbesione (1) and desoxymorellin (3) is presented. Central to the strategy is a biomimetic Claisen/Diels–Alder/Claisen reaction cascade that proceeds in a regioselective manner and produces the desired scaffold exclusively.
Autor:
Sun Hee Kim, Emmanuel A. Theodorakis, Chinmay Chowdhury, Eric J. Tisdale, Binh G. Vong, Hongmei Li
Publikováno v:
ChemInform. 34
A convergent strategy toward the synthesis of lateriflorone ( 5 ) is described. Our approach is based on biosynthetic considerations and draws on a sequence of prenylation, oxygenation and Claisen reactions for the construction of chromenequinone 6 ,
Publikováno v:
ChemInform. 34
A total synthesis of atroviridin ( 1 ) based on biosynthetic principles is presented. The tetracyclic xanthone structure of the natural product was constructed by coupling aryl bromide 8 with aldehyde 7 and subsequent intramolecular conjugate additio