Crystal structure of (±)-1-({[4-(allyloxy)phenyl]sulfanyl}methyl)-2-(diphenylthiophosphoryl)ferrocene

Autor: Audric Michelot, Stéphanie Sarda, Jean-Claude Daran, Eric Deydier, Eric Manoury

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 8, Pp 972-975 (2015)

The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(allyloxy)phenyl]sulfanyl}methyl and diphenylthiophosphoryl groups, respectively. The two S atoms lie on opposite sides of th

Externí odkaz: https://doaj.org/article/6253086fca5e487295faf240e0ade4ae

Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes

Autor: Rinaldo Poli, Tat'yana A. Peganova, Alexander M. Kalsin, Eric Deydier, Natalia V. Belkova, Iana S. Sinopalnikova, Ivan V. Fedyanin

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2020, 49 (5), pp.1473-1484. ⟨10.1039/c9dt04532e⟩
Dalton Transactions, 2020, 49 (5), pp.1473-1484. ⟨10.1039/c9dt04532e⟩

International audience; A series of arene ruthenium iminophosphonamide complexes, [(Arene)RuCl{R2P(NR′)2}] (1), bearing various arenes and R,R′ substituents on the NPN ligand have been investigated as precatalysts in acetophenone transfer hydroge

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9e3202a302227bde37707cc764f4edee
https://doi.org/10.1039/c9dt04532e

Phosphine/N-heterocyclic carbene palladium complex for Suzuki-Miyaura cross-coupling reactions: The role of water on activity

Autor: Agnès Labande, Rinaldo Poli, Youssra Doria Lahneche, Eric Deydier, Jean-Claude Daran, Eric Manoury, Clément Mouton, Meriem Benslimane, Abdelhak Lachguar

Publikováno v: Inorganica Chimica Acta
Inorganica Chimica Acta, Elsevier, 2019, 492, pp.91-97. ⟨10.1016/j.ica.2019.04.021⟩
Inorganica Chimica Acta, 2019, 492, pp.91-97. ⟨10.1016/j.ica.2019.04.021⟩

International audience; A new bidentate ferrocenyl phosphine/N-heterocyclic carbene (NHC) palladium complex rac-6, bearing a functionalized pendant arm for further grafting on a solid surface, has been synthesized in good yields and fully characteriz

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::01dab8f3586973707d600ebb3fa8befb
https://hal.archives-ouvertes.fr/hal-02333616

Ruthenium p-cymene iminophosphonamide complexes: Activation under basic conditions and transfer hydrogenation catalysis

Autor: Rinaldo Poli, Natalia V. Belkova, Iana S. Sinopalnikova, Alexander M. Kalsin, Tat'yana A. Peganova, Eric Deydier, Jean-Claude Daran, Elena S. Shubina

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2018, 2018 (20-21), pp.2285-2299. ⟨10.1002/ejic.201701344⟩
European Journal of Inorganic Chemistry, 2018, 2018 (20-21), pp.2285-2299. ⟨10.1002/ejic.201701344⟩

International audience; Complex [(η6-Cym)RuCl(NPN)] Cym = p-cymene; NPN = (pTolN)2PPh2 (1) yields a thermally sensitive hydride derivative [(η6-Cym)RuH(NPN)] (2) by reaction with iPrOH in the presence of a strong base, via an observable isopropoxid

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7708cafddecab3584e8201b460728795
https://hal.archives-ouvertes.fr/hal-01954087

The cocrystalrac-1-[(N,4-dimethylbenzenesulfonamido)methyl]-2-(diphenylphosphoryl)ferrocene–rac-1-[(N,4-dimethylbenzenesulfonamido)methyl]-2-(diphenylphosphanyl)ferrocene (0.45/0.55)

Autor: Muh Mei Wei, Catherine Audin, Eric Manoury, Eric Deydier, Jean Claude Daran

Publikováno v: Acta Crystallographica Section C: Crystal Structure Communications
Acta Crystallographica Section C: Crystal Structure Communications, 2014, 70 (3), pp.281-284. ⟨10.1107/S2053229614002988⟩

As part of our interest in the synthesis and catalytic applications of chiral (diphenylphosphanyl)ferrocene ligands, we designed a number of P,N-containing ligands for use in asymmetric transfer hydrogenation (ATH). During the synthetic procedure to

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7270fd9f1a4c4a172325cb9a1829a3cb
https://doi.org/10.1107/s2053229614002988