Determination of the dehydration pathway in a flexible metal–organic framework by dynamic in situ x-ray diffraction

Autor: Ian M. Walton, Jordan M. Cox, Shea D. Myers, Cassidy A. Benson, Travis B. Mitchell, Gage S. Bateman, Eric D. Sylvester, Yu-Sheng Chen, Jason B. Benedict

Publikováno v: Structural Dynamics, Vol 7, Iss 3, Pp 034305-034305-7 (2020)

Understanding guest exchange processes in metal–organic frameworks is an important step toward the rational design of functional materials with tailor-made properties. The dehydration of the flexible metal-organic framework [Co(AIP)(bpy)0.5(H2O)]�

Externí odkaz: https://doaj.org/article/ac4506c43a05428c864bd1803d9538f7

Synthesis and Characterization of Photoactive Methyl 4-Bromo-3-((2,6-Difluorophenyl)diazenyl) Benzoate

Autor: Eric D. Sylvester, Jason B. Benedict

Publikováno v: Journal of Chemical Crystallography. 51:582-590

The synthesis and structure of a novel ortho-fluoroazobenzene, methyl 4-bromo-3-((2,6-difluorophenyl)diazenyl) benzoate is described. The title molecule crystallizes in the centrocemetric space group P-1 with two rotomer molecules of the title compou

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b38746dbac71b8f04506a19067c80508
https://doi.org/10.1007/s10870-021-00881-6

Partial charge transfer in the salt co-crystal of l-ascorbic acid and 4,4′-bi­pyridine

Autor: Mitchell McGovern, Phanxico Nguyen, Jason B. Benedict, Eric D. Sylvester, An Young Lee, Jungeun Park

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 6, Pp 728-731 (2019)

In the title 1:2 co-crystal, l-ascorbic acid (LAA) and 4,4′-bi­pyridine (bpy) co-crystallize with two mol­ecules of LAA, and one mol­ecule of bpy in the asymmetric unit. The structure was modeled in two parts due to possible proton transfer from

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::606fb6c7c3fb77f048c299eb2d4404f3
http://europepmc.org/articles/PMC6658955

Phonon Kinetics at the Solid to Liquid Phase Transition

Autor: Erik Einarsson, Eric D. Sylvester, Deepu George, Andrea Markelz, Jason B. Benedict, Farah Vandrevala, Alex Davie, Timothy M. Korter, Yanting Deng

Publikováno v: 2020 45th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz).

Terahertz time domain spectroscopy is used to measure the melting kinetics of fructose molecular crystals. Combining single crystal anisotropy measurements with density functional calculations we assign the phonon frequencies and interrogate how spec

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cf2aabf0464d700bdcf07b199e173bfb
https://doi.org/10.1109/irmmw-thz46771.2020.9370643

Determination of the dehydration pathway in a flexible metal–organic framework by dynamic in situ x-ray diffraction

Autor: Cassidy A. Benson, Eric D. Sylvester, Ian M. Walton, Jordan M. Cox, Shea D. Myers, Travis Mitchell, Jason B. Benedict, Yu-Sheng Chen, Gage Bateman

Publikováno v: Structural Dynamics
Structural Dynamics, Vol 7, Iss 3, Pp 034305-034305-7 (2020)

Understanding guest exchange processes in metal–organic frameworks is an important step toward the rational design of functional materials with tailor-made properties. The dehydration of the flexible metal-organic framework [Co(AIP)(bpy)0.5(H2O)]�

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::481038aaffaa9f64bd659fdac4ea2f77
https://doi.org/10.1063/4.0000015