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Regioselective Metal Exchange Reactions in Linked Clusters

Autor: Yuan-Qi Yin, Yu-Hua Zhang, Xue-Nian Chen, Jie Zhang, and Er-Run Ding

Publikováno v: Organometallics. 19:5032-5038

Regioselective metal exchange reactions in linked clusters, [(CO)9Co3(μ3-C)COOCH2]2 (1) and (CO)9Co3(μ3-C)COOCH2(μ-CCH)Co2(CO)6 (2), were investigated. The reactions of 1 with Na[M(CO)3(C5H4R)] (M ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::060d673efab7bd31f478c745aba36894
https://doi.org/10.1021/om000627q

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Syntheses and Reactions of Dimolybdenum Alkyne Compounds Containing Functionally Substituted Ligands. The Crystal Structure of [Co2Mo2(μ4-CHCH)(μ-CO)4(CO)4-(η5-C5H4C(O)Me)2]

Autor: Xue-Nian Chen, Er-Run Ding, Jie Zhang, Yuan-Qi Yin

Publikováno v: Journal of Coordination Chemistry. 51:283-291

Three dimolybdenum alkyne complexes containing functionally substituted ligands [Mo2(μ-CHCH)(CO)4(η5‒C5H4C(O)R)2] [R ˭ OEt, (1a); R ˭ Me, (1b); R ˭ Ph, (1c)] were synthesized by reactions of acetylene with in situ generated metal-metal triply

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::75e08f35a28fe89374091f4dc8a7de3b
https://doi.org/10.1080/00958970008055134

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Syntheses and Reactions of Dimolybdenum Propargyl Alcohol Compounds Containing Functionally Substituted Ligands

Autor: Er-Run Ding, Yuan-Qi Yin, Jie Zhang, Xue-Nian Chen

Publikováno v: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 30:1221-1235

Several dimolybdenum propargyl alcohol compounds containing functionally substituted cyclopentadienyl ligands, [Mo2(μ-CHCCH2OH)(CO)4., (η5-C5H4C(O)R)2] [R = OEt, (1); R = Me, (2); R = Ph, ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::91f36cdd9a3394c817859c946ce6c91f
https://doi.org/10.1080/00945710009351830

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Synthesis and Reaction of New Metal Cluster Complexes Containing a Wrucose Core

Autor: Yu-Hua Zhang, Xue-Nian Chen, Cui-Ping Song, Er-Run Ding, Jie Zhang, Yuan-Qi Yin, Jie Sun

Publikováno v: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 29:1315-1329

Several chiral cluster derivatives, RuCoW(μ3Se)(CO)8{η5-C5H4C(O)R} [R = H (2), CH3 (3), C6H5 (4), C6H5C(O)OCH3 (5)], were” synthesized by reaction of the precursor (μ3-Se)RuCo2(CO)t) (1) with the functionally substituted cyclopentadienyl tricarb

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d3804671b0faf32165a1ecef05e99b7f
https://doi.org/10.1080/00945719909351701

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Reaction of dipropargyl phthalate with Co2(CO)8 and Mo2Cp2(CO)4 gives the di or tetranuclear clusters. The crystal structure of [C6H4-1,2-(CO2CH2C2H-μ)2][Co2(CO)6]2 and [o-(HC2CH2OCO)C6H4(CO2CH2C2H-μ)][Mo2Cp2(CO)4]–CH2Cl2

Autor: Yuan-Qi Yin, Jie Sun, Xue-Nian Chen, Er-Run Ding, Jie Zhang

Publikováno v: Polyhedron. 18:1555-1560

The reaction of dipropargyl phthalate with Co2(CO)8 in benzene at room temperature gave a new cluster [C6H4-1,2-(CO2CH2C2H-μ)2][Co2(CO)6]2 1, which reacts with the cyclopentadienyl tricarbonyl molybdenum anion [Mo(CO)3Cp]− to form the tetranuclear

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::38dc48a05cc2989e8d27af56b67ba906
https://doi.org/10.1016/s0277-5387(99)00022-4

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Reaction of (μ3-Se)RuCo2(CO)9: Synthesis and Crystal Structure of the Chiral Skeleton Clusters (μ3-Se)RuCoM(CO)8[C5H3(CH3)(COCH3)] (M=Mo, W)

Autor: Er-Run Ding, Jie Sun, Qing-Shan Li, Yuan-Qi Yin, Shu-Lin Wu

Publikováno v: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 29:565-575

The reaction of (μ3-Se)RuCo2(CO)9 (1) with the functionally substituted cyclopentadienyl tricarbonyl metal anions M(CO)3C5H3[(CH3)(COCH3)] (M = Mo, W) in reluxing THF gave new chiral skeleton clusters (μ3-Se)RuCoM(CO)8[C5H3(CH3)(COCH3)] [M = Mo (4)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b1cff541ca3c32f8f8c2d3943fd847e0
https://doi.org/10.1080/00945719909349471

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Synthesis, molecular structure and radical scavenging effect of octanuclear thiolate zinc complex [NMe4]2[(c-μ4-S)(μ-SCH2Ph)12S4Zn8]

Autor: Shengli Guo, Yuan-Qi Yin, Hua Chen, Er-Run Ding, Xianjun Li

Publikováno v: Polyhedron. 18:735-740

The new cage-like octanuclear thiolate complex [NMe4]2[(c-μ4-S)(μ-SCH2Ph)12S4Zn8] has been prepared and characterized by X-ray crystal structure analysis All eight Zn atoms and a μ4-S constitute a tetracapped tetrahedron in which μ4-S is at the c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::73998ff0ec681b65d682c2e6dd6c1a99
https://doi.org/10.1016/s0277-5387(98)00347-7

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Synthesis and expansion reaction of ferrocenylacetylene dimetal carbonyl compounds. The molecular structures of μ -FcCCHCoMo(CO) 5 Cp and μ 3 -FcCHCFeCo 2 (CO) 9

Autor: Er-Run Ding, Jie Sun, Yuan-Qi Yin, Shu-Lin Wu

Publikováno v: Journal of Organometallic Chemistry. 570:71-78

Two ferrocenylacetylene dimetal carbonyl clusters μ -FcCCHCo(CO) 3 M(CO) 2 Cp ( 2 , M=Mo; 3 , M=W) were obtained from the reactions of the precursor μ -FcCCHCo 2 (CO) 6 1 with metal exchange reagents NaM(CO) 3 Cp in THF under reflux. The dimetal co

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4880b39c7c818f16f06a9a5ec8e9b6d9
https://doi.org/10.1016/s0022-328x(98)00813-4

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