Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Ephrath Solel"'
Autor:
Yu-Sheng Chen, Ephrath Solel, Yi-Fan Huang, Chien-Lung Wang, Tsung-Han Tu, Ehud Keinan, Yi-Tsu Chan
Publikováno v:
Nature Communications, Vol 10, Iss 1, Pp 1-6 (2019)
The icosahedron, as the polyhedron closest in symmetry to the sphere, is one of the most compelling Platonic solids for chemists to construct. Here, the authors assemble a supramolecular icosahedron from twelve pentatopic corannulene-based tectons, a
Externí odkaz:
https://doaj.org/article/ef91ab1451204e8a9b49c5705400c065
Autor:
Ephrath Solel, Sebastian Kozuch
Publikováno v:
Molecules, Vol 23, Iss 11, p 2742 (2018)
Tetrel bonds are noncovalent interactions formed by tetrel atoms (as σ-hole carriers) with a Lewis base. Here, we present a computational and molecular orbital study on the effect of the geometry of the substituents around the tetrel atom on the σ-
Externí odkaz:
https://doaj.org/article/838d8670b162494a9aa3d46dc10e93f6
Autor:
Bastian Bernhardt, Ephrath Solel, Peter Richard Schreiner, André K. Eckhardt, Markus Schauermann
Publikováno v:
Chemical Science. 14:130-135
A novel heterosubstituted carbene spontaneously binds CO2 in a tunneling reaction under cryogenic conditions.
Autor:
Juliane Schoening, Chelladurai Ganesamoorthy, Christoph Wölper, Ephrath Solel, Peter R. Schreiner, Stephan Schulz
Publikováno v:
Dalton Transactions. 51:8249-8257
Room-temperature stable main group element carbonyl complexes are rare. Here we report on the synthesis of two such complexes, namely gallium-substituted silylene-carbonyl complexes [L(X)Ga]2SiCO (X = I 2, Me 3; L = HC[C(Me)NDipp]2, Dipp = 2,6-iPr2C6
Publikováno v:
Journal of the American Chemical Society. 143:20837-20848
We suggest a scale of dispersion energy donors (DEDs) that allows for direct comparisons with steric effects. This scale is based on the classic A-values and allows groups to reorient to minimize strain, thereby providing an advantage over raw group
Autor:
Qigang Zhong, Artur Mardyukov, Ephrath Solel, Daniel Ebeling, André Schirmeisen, Peter Schreiner
On-surface synthesis is at the verge of emerging as the method of choice for the generation and visualization of unstable or unconventional molecules, which could not be obtained via traditional synthetic methods. A case in point is the on-surface sy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dc71d0982c539860296de01fcd5b3891
https://doi.org/10.21203/rs.3.rs-2169632/v1
https://doi.org/10.21203/rs.3.rs-2169632/v1
Autor:
Bastian, Bernhardt, Markus, Schauermann, Ephrath, Solel, André K, Eckhardt, Peter R, Schreiner
Publikováno v:
Chemical science. 14(1)
The search for methods to bind CO
Autor:
Ehud Keinan, Doron Pappo, Ephrath Solel, Ofer Reany, Mark Botoshansky, Renana Gershoni-Poranne, Tom Mejuch, Amnon Stanger
Publikováno v:
Chemical Science
Flat corannulene has been considered so far only as a transition state of the bowl-to-bowl inversion process. This study was driven by the prediction that substituents with strong steric repulsion could destabilize the bowl-shaped conformation of thi
Publikováno v:
Chemistry – A European Journal. 26:625-628
Cyclo[18]carbon (C18 ), a recently synthesized carbon allotrope, was found to have a polyynic ground-state structure with D9h symmetry and formally alternating single and triple bonds. Yet, under less influencing experimental conditions this molecule
Publikováno v:
The Journal of organic chemistry. 86(11)
Halogens are rarely considered as dispersion energy donors for organic reaction design. Here, we re-examine one of the textbook examples for assessing steric hindrance, the A-value, and demonstrate that even in this system, halogens cannot be treated