Antimony speciation in aqueous solution followed with AGNES

Autor: P. Pla-Vilanova, Josep Galceran, Montserrat Filella, Jaume Puy, Encarnació Companys

Publikováno v: Journal of Electroanalytical Chemistry, Vol. 849 (2019) P. 113334
Repositorio Abierto de la UdL
Universitad de Lleida
Recercat. Dipósit de la Recerca de Catalunya
instname

Determining antimony speciation is essential to understand its environmental behaviour and potential (eco)toxicological effects. Absence of Gradients and Nemstian Equilibrium Stripping (AGNES) is an electroanalytical technique that has been applied u

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::516964d54b7d9af6d3f1940d1cb0b290
https://archive-ouverte.unige.ch/unige:122538

The Impact of Intermetallic Compounds CuxZn in the Determination of Free Zn2+ Concentration with AGNES

Autor: Encarnació Companys, Josep Galceran, Diana Chito

Publikováno v: Electroanalysis. 22:2024-2033

Intermetallic compounds can interfere the determination of free Zn with AGNES (Absence of Gradients and Nernstian Equilibrium Stripping). The “trajectory” (plot of the retrieved currents in front of the deposition times) diverges from the “refe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::968cd192a2db5d23e2a062b003ef2fd9
https://doi.org/10.1002/elan.201000078

Conditional affinity spectra underlying NICA isotherm

Autor: Jaume Puy, Josep Galceran, C. Huidobro, Francesc Mas, José Salvador, Encarnació Companys, Carlos Rey-Castro, Calin David, J. L. Garces, Joan Cecília

Publikováno v: Colloids and Surfaces A: Physicochemical and Engineering Aspects. 347:156-166

The properties of the NICA (non-ideal competitive adsorption) isotherm are examined from the point of view of the underlying conditional affinity spectra (CAS), the distribution of effective affinities seen by a given metal ion at a fixed pH. It is s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b5230795d3b838da44c2b6dc645a3832
https://doi.org/10.1016/j.colsurfa.2009.03.053

Competitive Cd2+/H+ Complexation to Polyacrylic Acid Described by the Stepwise and Intrinsic Stability Constants

Autor: Francesc Mas, Calin David, Jaume Puy, Josep Galceran, José Salvador, Encarnació Companys, Carlos Rey-Castro, Josep Lluís Garcés

Publikováno v: The Journal of Physical Chemistry B. 112:10092-10100

Stepwise constants can be used to describe competitive proton and metal binding to macromolecules with a large number of sites. With the aim of accessing information on the microscopic binding model, we report an expression that connects the stepwise

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9352db2f1e97e9bfa81ddd2ec6d03f4
https://doi.org/10.1021/jp802571f

Ligand Mixture Effects in Metal Complex Lability

Autor: Joan Cecília, Josep Galceran, J. L. Garces, Raewyn M. Town, Encarnació Companys, Jaume Puy, José Salvador

Publikováno v: Salvador, J, Garcés, J L, Companys, E, Cecília, J, Galceran, J, Puy, J & Town, R M 2007, ' Ligand mixture effects in metal complex lability ', Journal of Physical Chemistry A, vol. 111, no. 20, pp. 4304-4311 . https://doi.org/10.1021/jp0707844

The degree of lability of a given metal complex species is modified in the presence of a mixture of ligands. This modification is a consequence of the coupling of the association and dissociation processes of all of the complexes according to the com

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3cb44cf85b8c39dbc00eee0531d61b72
https://doi.org/10.1021/jp0707844