Spin Cross-Over (SCO) Anionic Fe(II) Complexes Based on the Tripodal Ligand Tris(2-pyridyl)ethoxymethane

Autor: Emmelyne Cuza, Samia Benmansour, Nathalie Cosquer, Françoise Conan, Sébastien Pillet, Carlos J. Gómez-García, Smail Triki

Publikováno v: Magnetochemistry, Vol 6, Iss 2, p 26 (2020)

Reactions of Fe(II) with the tripodal chelating ligand 1,1,1-tris(2-pyridyl)ethoxymethane (py3C-OEt) and (NCE)− co-ligands (E = S, Se, BH3) give a series of mononuclear complexes formulated as [Fe(py3C-OEt)2][Fe(py3C-OEt)(NCE)3]2·2CH3CN, with E =

Externí odkaz: https://doaj.org/article/ff0e0fa9d26e4f3cba34f2c2d7aaa3fb

Antagonist elastic interactions tuning spin crossover and LIESST behaviours in FeII trinuclear-based one-dimensional chains

Autor: Narsimhulu Pittala, Emmelyne Cuza, Dawid Pinkowicz, Michał Magott, Mathieu Marchivie, Kamel Boukheddaden, Smail Triki

Publikováno v: Inorganic Chemistry Frontiers. 9:6468-6481

A new 1-D spin SCO coordination polymer based on FeII trinuclear units covalently linked by a flexible coligand has been reported as an unusual platform and model system for experimental study on the origin of the step-like feature in 1-D systems.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::37ce265b7bb73cbb02fcb3d469638a43
https://doi.org/10.1039/d2qi01629j

Solvent-Induced Hysteresis Loop in Anionic Spin Crossover (SCO) Isomorph Complexes

Autor: Samia Benmansour, Carlos J. Gómez-García, Françoise Conan, Nathalie Cosquer, Emmelyne Cuza, Smail Triki

Publikováno v: Magnetochemistry, Vol 7, Iss 75, p 75 (2021)
Magnetochemistry
Volume 7
Issue 6

Reaction of Fe(II) with the tris-(pyridin-2-yl)ethoxymethane (py3C-OEt) tripodal ligand in the presence of the pseudohalide ancillary NCSe− (E = S, Se, BH3) ligand leads to the mononuclear complex [Fe(py3C-OEt)2][Fe(py3C-OEt)(NCSe)3]2·2CH3CN (3),

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f9b689376d0a76f515d0d24d901708d
https://doi.org/10.20944/preprints202104.0467.v1

Spin Cross-Over (SCO) Anionic Fe(II) Complexes Based on the Tripodal Ligand Tris(2-pyridyl)ethoxymethane

Autor: Sébastien Pillet, Samia Benmansour, Smail Triki, Nathalie Cosquer, Emmelyne Cuza, Françoise Conan, Carlos J. Gómez-García

Publikováno v: Magnetochemistry, Vol 6, Iss 26, p 26 (2020)
Magnetochemistry
Volume 6
Issue 2
Magnetochemistry, MDPI, 2020, ⟨10.3390/magnetochemistry6020026⟩

Reactions of Fe(II) with the tripodal chelating ligand 1,1,1-tris(2-pyridyl)ethoxymethane (py3C-OEt) and (NCE)&minus
co-ligands (E = S, Se, BH3) give a series of mononuclear complexes formulated as [Fe(py3C-OEt)2][Fe(py3C-OEt)(NCE)3]2·