Mechanistic insights into the formation of polyion complex aggregates from cationic thermoresponsive diblock copolymers

Autor: E. Di Cola, Emmanuelle Read, Jean-Daniel Marty, Anne-Françoise Mingotaud, Patrice Castignolles, Adam T. Sutton, Barbara Lonetti, Marianne Gaborieau, Mathias Destarac, Stéphane Gineste

Publikováno v: Journal of Colloid and Interface Science
Journal of Colloid and Interface Science, Elsevier, 2021, 590, pp.268-276. ⟨10.1016/j.jcis.2021.01.028⟩
Journal of Colloid and Interface Science, 2021, 590, pp.268-276. ⟨10.1016/j.jcis.2021.01.028⟩

Hypothesis: The formation of polyion complexes (PICs) comprising thermoresponsive polymers is intended to result in the formation of aggregates that undergo significant structural changes with temperature. Moreover the observed modifications might be

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e71d7eb7e6763397ad4f3880f1f9842
https://hal.archives-ouvertes.fr/hal-03130969

Low temperature RAFT/MADIX gel polymerisation: access to controlled ultra-high molar mass polyacrylamides

Autor: Aymeric Guinaudeau, Frédéric Violleau, Arnaud Cadix, Emmanuelle Read, D. James Wilson, Mathias Destarac

Publikováno v: Polymer Chemistry
Polymer Chemistry, Royal Society of Chemistry-RSC, 2014, 5 (7), pp.2202. ⟨10.1039/C3PY01750H⟩

We pushed back the limits of molar mass control in aqueous RAFT/MADIX polymerisation through a fast and quantitative gel polymerisation of a series of acrylamido monomers. Unprecedentedly high Mn up to 106 g mol−1 with low dispersities (Đ < 1.2) w

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59332f1c30fb1677a190e493c195bc93
https://doi.org/10.1039/c3py01750h