Some Chemical Properties of Monochlorogallane: Decomposition to Gallium(I) Trichlorogallate(III), Ga+[GaCl3H]-, and Other Reactions

Autor: Michael J. Goode, Hans-Jörg Himmel, Matthias Müller, Anthony J. Downs, Emma Johnsen, Timothy M. Greene, Colin R. Pulham, Simon Parsons

Publikováno v: Inorganic Chemistry. 40:4755-4761

Thermal decomposition of monochlorogallane, [H2GaCl]n, at ambient temperatures releases H2 and results in the formation of gallium(I) species, including the new compound Ga[GaHCl3], which has been characterized crystallographically at 100 K (monoclin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a9bdfc0a556a57b35d1c81088ca8cb1e
https://doi.org/10.1021/ic010128x

Monochlorogallane: Physical Properties and Structure of the Gaseous Molecule H2Ga(μ-Cl)2GaH2 As Determined by Vibrational, Electron Diffraction, and ab Initio Studies

Autor: Elizabeth M. Page, Colin R. Pulham, Philip F. Souter, Timothy M. Greene, Anthony J. Downs, Emma Johnsen, Kirsten Aarset, Alan N. Richardson, David A. Rice, Paul T. Brain, David W. H. Rankin

Publikováno v: Inorganic Chemistry. 39:719-727

Monochlorogallane, synthesized by the metathesis of gallium(III) chloride with an excess of trimethylsilane at ca. 250 K, has been characterized by chemical analysis, by its IR, Raman, and 1H NMR spectra, and by the products of its reaction with trim

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c57ee2167c30f8ac5678f6bb4a2e2a38
https://doi.org/10.1021/ic9908975

Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids

Autor: Emma Johnsen, Roger M. G. Roberts

Publikováno v: Journal of Organometallic Chemistry. 544:197-205

[(η-Substituted arene)(η-cyclopentadienyl)Fe][PF6] complexes with amino acid side chains on the arene ring have been prepared by reaction of [(η-haloarene)(η-cyclopentadienyl)Fe][PF6] complexes with amino acids and amino acid esters under various

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d57f4812750cd1ca1d1006dbfde8a965
https://doi.org/10.1016/s0022-328x(97)00292-1

The digallane molecule, Ga2H6: experimental update giving an improved structure and estimate of the enthalpy change for the reaction Ga2H6(g) → 2GaH3(g)

Autor: Derek A. Wann, Colin R. Pulham, Anthony J. Downs, Heather E. Robertson, Tim M. Greene, Emma Johnsen

Publikováno v: Downs, A J, Greene, T M, Johnsen, E, Pulham, C R, Robertson, H E & Wann, D A 2010, ' The digallane molecule, Ga 2 H 6 : experimental update giving an improved structure and estimate of the enthalpy change for the reaction Ga 2 H 6 (g) → 2GaH 3 (g) ', Dalton Transactions, vol. 39, no. 24, pp. 5637-5642 . https://doi.org/10.1039/c000694g

Improved methods of analysis and new quantum chemical calculations have been applied to the results of earlier gas-phase electron diffraction (GED) studies of digallane to give what is judged to be the most realistic structure available to date. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6c3a45e19b72e1aded5f3e6e7b64136
https://hdl.handle.net/20.500.11820/f5a6800b-afa9-48c5-ad30-a0f66a7bd46c