Crystal Engineering of Conglomerates: Dilution of Racemate-Forming Fe(II) and Ni(II) Congeners into Conglomerate-Forming [Zn(bpy)3](PF6)2

Autor: Ugo Serdan, Lucas Robin, Mathieu Marchivie, Mathieu Gonidec, Patrick Rosa, Elen Duverger-Nédellec, Emilie Pouget, Philippe Sainctavit, Marie-Anne Arrio, Amélie Juhin, Andrei Rogalev, Fabrice Wilhelm, Elizabeth A. Hillard

Publikováno v: Chemistry, Vol 5, Iss 1, Pp 255-268 (2023)

Conglomerate formation, where enantiomers within a racemic mixture self-segregate upon crystallization, is an advantageous property for obtaining chirally pure crystals and allows large-scale chiral resolution. However, the prevalence of conglomerate

Externí odkaz: https://doaj.org/article/8ba0210e1e3c4fec942fb6774d591041

Ferrocifens and Ferrocifenols as New Potential Weapons against Breast Cancer

Autor: Anh Nguyen, Anne Vessières, Elizabeth A. Hillard, Siden Top, Pascal Pigeon, Gérard Jaouen

Publikováno v: CHIMIA, Vol 61, Iss 11 (2007)

Depending on the presence or absence of the estrogen receptor in the cells, breast cancer today is often treated by endocrine therapy (tamoxifen) or chemotherapy, respectively. We present now a new paradigm for breast cancer treatment, taking advanta

Externí odkaz: https://doaj.org/article/f28282164baf46a9b8d97474215b5a14

Design of Binary Nb2O5–SiO2 Self-Standing Monoliths Bearing Hierarchical Porosity and Their Efficient Friedel–Crafts Alkylation/Acylation Catalytic Properties

Autor: Isabelle Ly, Elodie Layan, Emmanuel Picheau, Nicolas Chanut, Frédéric Nallet, Ahmed Bentaleb, Marie-Anne Dourges, Roland J. Pellenq, Elizabeth A. Hillard, Thierry Toupance, François Dole, Frédéric Louërat, Rénal Backov

Publikováno v: ACS Applied Materials & Interfaces. 14:13305-13316

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c237f5723864e78a96ebcf90ba179ee0
https://doi.org/10.1021/acsami.1c24554

Validation of microscopic magnetochiral dichroism theory

Autor: Ángela Valentín-Pérez, Patrick Rosa, Jochen Autschbach, Kévin Paillot, Geert L. J. A. Rikken, Matteo Atzori, Elizabeth A. Hillard, Ivan Breslavetz, Miguel Cortijo, Cyrille Train, Herbert D. Ludowieg

Publikováno v: Science Advances
Science Advances, American Association for the Advancement of Science (AAAS), 2021, 7 (17), eabg2859 (8 p.). ⟨10.1126/sciadv.abg2859⟩
Science Advances, 2021, 7 (17), eabg2859 (8 p.). ⟨10.1126/sciadv.abg2859⟩

The union between magnetism and chirality is finally validated.
Magnetochiral dichroism (MChD), a fascinating manifestation of the light-matter interaction characteristic for chiral systems under magnetic fields, has become a well-established op

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cfb98c01385dce29be79f2df2fed93a9
https://hal.archives-ouvertes.fr/hal-03213607/file/2021-064.pdf

Magneto‐chiral anisotropy: From fundamentals to perspectives

Autor: Elizabeth A. Hillard, Cyrille Train, Matteo Atzori, Geert L. J. A. Rikken, Narcis Avarvari

Publikováno v: Chirality
Chirality, Wiley, 2021, 33 (12), pp.844-857. ⟨10.1002/chir.23361⟩
Chirality, 2021, 33 (12), pp.844-857. ⟨10.1002/chir.23361⟩

International audience; The interplay between chirality and magnetic fields gives rise to a cross effect referred to as magnetochiral anisotropy (MChA), which can manifest itself in different physical properties of chiral magnetized materials. The fi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67d44ba935be8aad9a79851e4748050b
https://hal.archives-ouvertes.fr/hal-03402567/document