Mechanochemical Syntheses of Ln(hfac)

Autor: Deepthi Y, Chappidi, Matthew N, Gordon, Hannah M, Ashberry, Junjie, Huang, Bruce M, Labedis, Riley E, Cooper, Brandon J, Cooper, Veronica, Carta, Sara E, Skrabalak, Kim R, Dunbar, Elisabeth M, Fatila

Publikováno v: Inorganic chemistry. 61(31)

Volatile lanthanide coordination complexes are critical to the generation of new optical and magnetic materials. One of the most common precursors for preparing volatile lanthanide complexes is the hydrate with the general formula Ln(hfac)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d904ea7173b55256e9dafda9e7ea7abc
https://pubmed.ncbi.nlm.nih.gov/35892174

Phosphate–phosphate oligomerization drives higher order co-assemblies with stacks of cyanostar macrocycles

Autor: Maren Pink, Jonathan A. Karty, Elisabeth M. Fatila, Eric B. Twum, Amar H. Flood

Publikováno v: Chemical Science. 9:2863-2872

The importance of phosphate in biology and chemistry has long motivated investigation of its recognition. Despite this interest, phosphate's facile oligomerization is only now being examined following the discovery of complexes of anion–anion dimer

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::aa8f1d9d944fa0a5abc2e8d589804453
https://doi.org/10.1039/c7sc05290a

Extreme Stabilization and Redox Switching of Organic Anions and Radical Anions by Large-Cavity, CH Hydrogen-Bonding Cyanostar Macrocycles

Autor: Michelle B. Mills, Matthew G. Marzo, Kathryn E. Preuss, Amar H. Flood, Christopher R. Benson, Semin Lee, Maren Pink, Elisabeth M. Fatila

Publikováno v: Journal of the American Chemical Society. 138:15057-15065

Encapsulation of unstable guests is a powerful way to enhance their stability. The lifetimes of organic anions and their radicals produced by reduction are typically short on account of reactivity with oxygen while their larger sizes preclude use of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6079f5ed5c1acd00d25089fa5b25353f
https://doi.org/10.1021/jacs.6b09459

Ferromagnetic ordering of –[Sm(iii)-radical]n– coordination polymers

Autor: Kathryn E. Preuss, Adam C. Maahs, Mathieu Rouzières, Rodolphe Clérac, Elisabeth M. Fatila, Dmitriy V. Soldatov, Michelle B. Mills

Publikováno v: Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2016, 52, pp. 5414-5417. ⟨10.1039/c6cc01548d⟩

International audience; [Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering;TC = 3 K. The [Sm(III)-radical]n species is soluble in common organic solvents and can be sub

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e0337b02c5e6cb242517901b890e68f
https://doi.org/10.1039/c6cc01548d

Inchworm movement of two rings switching onto a thread by biased Brownian diffusion represent a three-body problem

Autor: Amar H. Flood, Abhishek Singharoy, Elisabeth M. Fatila, Christopher Maffeo, Yun Liu, Edward G. Sheetz, Aleksei Aksimentiev, Christopher R. Benson

Publikováno v: Proceedings of the National Academy of Sciences of the United States of America. 115(38)

The coordinated motion of many individual components underpins the operation of all machines. However, despite generations of experience in engineering, understanding the motion of three or more coupled components remains a challenge, known since the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ffaed05de8328fb8cfda2e6c6ad61724
https://pubmed.ncbi.nlm.nih.gov/29735677