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Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 7, Pp 1082-1086 (2017)
The title complex, [CuII(ClO4)(mesoPYBP)](ClO4) {PYBP = 1,1′-bis[(pyridin-2-yl)methyl]-2,2′-bipiperidyl, C22H30N4}, was prepared and found to crystallize with two crystallographically independent complex salt moieties. The metal atoms of the cati
Externí odkaz:
https://doaj.org/article/d05ede074e5b45faa20b260e8bc32b3b
Autor:
Edward Gabrielle V. Hilvano, Guang Yang, Inno A. Emnacen, Elena V. Rybak-Akimova, Junie B. Billones, Maria Constancia O. Carrillo, Bruce C. Noll, Voltaire G. Organo
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 1009-1012 (2016)
The title copper(II) complex of a pyridine-containing macrocycle (PyMAC), [Cu(C16H28N4)](ClO4)2, has been prepared. The crystal structure reveals the CuII atom to be octahedrally coordinated by a tetradentate aminopyridine macrocyclic ligand surround
Externí odkaz:
https://doaj.org/article/a01f61cee88f4e2ba2d9ab6690b89a68
Autor:
Guang Yang, Elena A. Mikhalyova, Alexander S. Filatov, Sergiy V. Kryatov, Elena V. Rybak-Akimova
Publikováno v:
Inorganica Chimica Acta. 546:121288
Autor:
Reza Latifi, Kwame S. Glinton, Laleh Tahsini, Sam P. de Visser, Elena V. Rybak-Akimova, Jennifer L. Minnick, Wanhua Ye, Taryn D. Palluccio
Publikováno v:
Inorganic chemistry. 60(18)
Nonheme iron enzymes often utilize a high-valent iron(IV) oxo species for the biosynthesis of natural products, but their high reactivity often precludes structural and functional studies of these complexes. In this work, a combined experimental and
Publikováno v:
Inorganic Chemistry. 58:13382-13393
Oxoiron(IV) is a common catalytic byproduct observed in the oxidation of alkenes by the combination of H2O2 and nonheme iron catalysts including complex 1, FeIIPDP* (where PDP* = bis(3,5-dimethyl-4...
Publikováno v:
Organometallics. 38:2512-2522
The acetamide-benzonitrile and benzonitrile self-condensation reactions promoted by nickel(II) hydroxy dimer 1, [Ni2(tBuDPA)2(μ-OH)2](ClO4)2 (tBuDPA = bis(2-methylpyridine)tert-butylamine), for the...
Publikováno v:
Acta Crystallographica Section E, Vol 69, Iss 11, Pp o1711-o1711 (2013)
The title compound, C10H22N22+·2Br−, was synthesized via reduction of 2,2′-dipyridyl with Ni–Al alloy/KOH, followed by separation of diastereoisomers (meso and rac) by recrystallization from ethanol. Although the two bridging C atoms are optic
Externí odkaz:
https://doaj.org/article/e4c08a95ffd94267a8a9305a01a393f3
Publikováno v:
Inorganica Chimica Acta. 482:732-737
A copper-containing pyridine-aza macrocycle (PyMAC) with a propionic acid functionality was synthesized and characterized using X-ray crystallography and various spectroscopic techniques. The complex was then screened for peroxidase, olefin epoxidati
Autor:
Vladimir A. Basiuk, Lina M. Bolivar-Pineda, Elena V. Basiuk, Elena V. Rybak-Akimova, Victor Meza-Laguna
Publikováno v:
The Journal of Physical Chemistry Letters. 9:4420-4427
Unsubstituted phthalocyanines (including free-base H2Pc and many of its metal complexes) are among the most stable organic compounds. They can sublime without decomposition under reduced pressure and temperatures of up to 550 °C. This property was p