Výsledky vyhledávání - "Elaine F. Hills"

Kinetic studies on substitution reactions of Delepine's triangular mixed-valence iridium(III, IV, IV) complex triaqua(.mu.3-nitrido)(hexa-.mu.-sulfato)triiridate(4-)

Autor: David T. Richens, A. Geoffrey Sykes, Elaine F. Hills

Publikováno v: Inorganic Chemistry. 25:3144-3148

Substitution de coordinats sur les 3 sites H 2 O (1 sur chaque metal). Constantes de vitesse pour les 3 coordinats entrants: N 3 − , Cl − , Br − , NCS −

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0d6a7918472e02918b9b3fe36fbb572e
https://doi.org/10.1021/ic00238a010

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Kinetic studies on the perchlorate oxidation of aqua molybdenum(3+) and Mo(III)2

Autor: Christopher Sharp, Elaine F. Hills, A. Geoffrey Sykes

Publikováno v: Inorganic Chemistry. 25:2566-2569

Oxydation de [(H 2 O) 4 Mo(OH) 2 Mo(H 2 O) 4 ] 4+ en solutions acides, en [Mo 2 O 4 (H 2 O) 6 ] 2+

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::adfe99ceed7031fbf7af228631890376
https://doi.org/10.1021/ic00235a017

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Preparation of the incomplete cubane-type sulfur-capped Mo3O2S24+ aqua ion and x-ray structure of (pyH)5 [Mo3O2S2(NCS)9]·2H2O

Autor: P. Kathirgamanathan, Takashi Yamada, Hisao Kuroya, A. Geoffrey Sykes, Elaine F. Hills, Takashi Shibahara

Publikováno v: Inorganica Chimica Acta. 113:L19-L21

Le compose [Mo 3 O 2 S 2 (NCS) 9 ] 5− cristallise dans le systeme monoclinique, groupe P2 1 et la structure est affinee jusqu'a R=0,078

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dae72871ab24eef92c480a06f805947f
https://doi.org/10.1016/s0020-1693(00)82225-2

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Kinetics and mechanism of the reduction of rhodium(III) complexes Rh(H2O)5X2+ by chromium(2+)

Autor: Monika Moszner, Elaine F. Hills, A. Geoffrey Sykes

Publikováno v: Inorganic Chemistry. 25:339-341

Reduction of the yellow rhodium(III) ions (Rh(H/sub 2/O)/sub 6/)/sup 3 +/, (Rh(H/sub 2/O)/sub 5/Cl)/sup 2 +/, and (Rh(H/sub 2/O)/sub 5/Br)/sup 2 +/ by Cr/sup 2 +/ in aqueous HClO/sub 4/ solution to give green rhodium(II) aqua dimer Rh/sub 2//sup 4 +/

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dcbe309757d8c178542755f826efebfb
https://doi.org/10.1021/ic00223a021

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Kinetic studies on the reactions of aqua Mo3+ with O2 and ClO−4

Autor: Elaine F. Hills, A.G. Sykes

Publikováno v: Polyhedron. 5:511-512

Kinetic studies are reported for two fundamental reactions of the hexaaquamolybdenum(III) ion with O 2 and ClO − 4 .

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2f3990539a146b597b1edffeae68eab4
https://doi.org/10.1016/s0277-5387(00)84956-6

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Preparation and properties of the tungsten(V) aqua dimer [W2O4(H2O)6]2+: kinetic studies on the 1:1 reaction with NCS?

Autor: A. Geoffrey Sykes, Christopher Sharp, Elaine F. Hills

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :2293

A procedure is described for the preparation of chromatographically pure tungsten(V) aqua dimer, absorption maxima, λ/nm (Iµ/M–1 cm–1 per dimer), at 430 (193) and 340 (278), in 2 M p-toluenesulphonic acid (Hpts). The aqua ion is readily convert

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::10d0d562ebb242fcfdd2c1b0ac83e6f1
https://doi.org/10.1039/dt9870002293

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