Synthesis and characterization of Al@MOF materials

Autor: Tomas Lunde Jensen, John F. Moxnes, Jasmina Hafizovic Cavka, Eirin Langseth, Richard H. Heyn, Erik Unneberg, Bjørnar Arstad, Anna Lind, Ole Swang, Tor E. Kristensen

Publikováno v: Materials Chemistry and Physics. 226:220-225

The potential impregnation of Al(0) nanoparticles in the pores of three different metal-organic frameworks (MOFs), MIL-53-Al, HKUST-1, and UiO-67, was investigated through the suspension of the MOFs in AlH3·NMe2Et (1), followed by filtration, toluen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6784cf14fa4599e54f229ca9337d9478
https://doi.org/10.1016/j.matchemphys.2019.01.009

trans-Mutation at Gold(III): A mechanistic study of a catalytic acetylene functionalization via a double insertion pathway

Autor: Mats Tilset, Marte Sofie Martinsen Holmsen, David Balcells, Gábor Laurenczy, Richard H. Heyn, Eirin Langseth, Sigurd Øien-Ødegaard, Ainara Nova

Publikováno v: ACS Catalysis

The Au(III) complex Au(tpy)(OAcF)2 (OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) catalyzes the anti addition of trifluoroacetic acid (HOAcF) to acetylene to furnish vinyl trifluoroacetate. The Au(III) vinyl complex Au(tpy)(OAcF)(CH═CHOAcF) (vinyl grou

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2762e1c57dd83e5628d41042019e8dc3
http://hdl.handle.net/10852/64649

Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile

Autor: Eline Aasen Tråseth, David Balcells, Richard H. Heyn, Eirin Langseth, Sigurd Øien-Ødegaard, Ainara Nova, Mats Tilset, Marte Sofie Martinsen Holmsen

Publikováno v: Dalton transactions (Cambridge, England : 2003). 45(37)

Incorporation of the simple, readily available, building blocks ethylene, water and acetonitrile into Au(tpy)(OCOCF3)2 (tpy = 2-(p-tolyl)pyridine) in a one-step reaction leads to high yields of a new 6-membered ring gold(III) metallacycle complex. Th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5141897c19695288a3274abd38146463
https://pubmed.ncbi.nlm.nih.gov/27283880

Generation and Structural Characterization of a Gold(III) Alkene Complex

Autor: David Balcells, Werner Kaminsky, Margaret L. Scheuermann, Odile Eisenstein, Richard H. Heyn, Eirin Langseth, Karen I. Goldberg, Mats Tilset

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52, pp.1660-1663. ⟨10.1002/anie.201209140⟩

International audience; A Missing Gold Link: An Au(III) alkene complex has been prepared and characterized by NMR spectroscopy and X-ray crystallography. Its bonding features have been analyzed by DFT calculations and natural bond orbital (NBO) analy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::12f8444c8d452f38b34ba637eb428225
https://hal.archives-ouvertes.fr/hal-00785548