Zobrazeno 1 - 10 of 11 pro vyhledávání: '"Eilis A. Harron"'
1
Nucleophilic addition to a Sn(ii) imido cubane, [SnNR]4; a new route to heteroleptic stannates
Autor: Eilis A. Harron, Andrew D. Bond, Dominic S. Wright, Gavin T. Lawson, Mary McPartlin, Marta E. G. Mosquera
Publikováno v: Journal of the Chemical Society, Dalton Transactions. :3525-3528
Nucleophilic addition to Sn(II) imido cubanes provides a novel route to heteroleptic stannates, as exemplified by the formation of [{Sn(NHmmp)(OtBu)2}K·thf]2 (2) and [{Sn(MeNCH2CH2NMe)(NHmmp)}Li]∞ (3) from the in situ reactions of the imido Sn(II)
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b8fcf4759dc964181fb36369d21f9717
https://doi.org/10.1039/b204340h
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2
Effects of meta-substitution on aggregation in the cubanes [SnNR]4 {R = [2-Me-5-MeOC6H3], [2,5-(MeO)2C6H3] and [3,5-(MeO)2C6H3]}
Autor: Marta E. G. Mosquera, Dominic S. Wright, Alessio Ciulli, Gavin T. Lawson, Eilis A. Harron, Alan Bashall, Mary McPartlin
Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1046-1050
An investigation of the solid-state X-ray structures of the cubanes [SnN{2-Me-5-MeOC6H3}]4, (1), [SnN{2,5-(MeO)2C6H3}]4, (2), and [SnN{3,5-(MeO)2C6H3}]4, (3), containing meta-MeO substituents on their aromatic groups, shows that unprecedented modes o
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::aa3128628562af29cc6bfeba05570e71
https://doi.org/10.1039/b107425c
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3
Association and fragmentation of imidotin(II) complexes containing donor-functionalised peripheries; towards new three-dimensional main group metal ligands †
Autor: David Sáez, Marta E. G. Mosquera, Neil Feeder, Alan Bashall, Dominic S. Wright, Mary McPartlin, Eilis A. Harron
Publikováno v: Journal of the Chemical Society, Dalton Transactions. :4104-4111
Structural studies of a series of tin(II) imido cubanes, [SnNR]4, containing donor-functionalised organic substituents (R), have allowed the systematic investigation of the factors controlling and affecting association of these architypal tin(II) com
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c5db23c1548d826d3306ab44b8666f97
https://doi.org/10.1039/b005932n
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4
Synthesis and Structure of the Octanuclear Manganese(II) Cage [(η-Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2Pm)}]4 (Cp = C5H5, pm = Pyrimidine)
Autor: Richard A. Layfield, Carmen Soria Aluarez, Judith A. McAllister, Christopher M. Pask, Andrew D. Bond, Dominic S. Wright, Eilis A. Harron, and Jeremy M. Rawson
Publikováno v: Organometallics. 20:4135-4137
The 1:1 reaction of 2-NH2(4,6-Me2pm) with Cp2Mn in thf gives the novel heteroleptic imido/amido Mn(II) cage [(η-Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2pm)}]4 (1), composed of a central Mn(II) imido [Mn4{2-N(4,6-Me2pm)}4] core coordinated at the perip
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::29f7e715026cfddd441d3653794118d9
https://doi.org/10.1021/om010357r
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6
Formation of double cubanes [Sn(7)(NR)(8)] in the reactions of pyridyl and pyrimidinyl amines with Sn(NMe(2))(2): a synthetic and theoretical study
Autor: David Moncrieff, and Anthony D. Woods, David R. Armstrong, Neil Feeder, David Sáez, Mary McPartlin, Alexander D. Hopkins, Dominic S. Wright, Andrew David Bond, Francesca Benevelli, Elsje A. Quadrelli, Eilis A. Harron
Publikováno v: Inorganic chemistry. 41(6)
In contrast to the reactions of Sn(NMe(2))(2) with unfunctionalized primary amines (RNH(2)), which yield the simple imido Sn(II) cubanes [SnNR](4), the reactions of 2-pyridyl or 2-pyrimidinyl amines give the mixed-oxidation-state Sn(II)/Sn(IV) double
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23b3df8ceff9118c93b10ce4e15ee1de
https://pubmed.ncbi.nlm.nih.gov/11896718
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7
Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2and octanuclear [Mn8(L2)12(μ4-O)2] (L1= 2-HNC5H5N, L2= 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)
Autor: Dominic S. Wright, Andrew D. Bond, Jeremy M. Rawson, Paul T. Wood, Mary McPartlin, Marta E. G. Mosquera, Richard A. Layfield, Carmen Soria Alvarez, Dale Cave, Eilis A. Harron
Publikováno v: Chem. Commun.. :2980-2981
The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(μ4-O)2] (2); magnetic measurements on
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e26db04384deb20f1afc2173379d78b6
https://doi.org/10.1039/b209496g
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8
Synthesis and structure of [Sn9(Ndmp)7(HNdmp)2O2], containing a bidentate double-cubane oxo fragment (H2Ndmp= 2-amino-4,6-dimethoxypyrimidine
Autor: Dominic S. Wright, Anthony D. Woods, Eilis A. Harron, Marta E. G. Mosquera, Neil Feeder
Publikováno v: Chemical Communications. :1010-1011
The reaction of Sn(NMe2)2 with H2Ndmp (H2Ndmp = 2-amino-4,6-dimethoxypyrimidine) and H2O (ca. 4∶4∶1 equivalents, respectively) gives the cage complex [Sn9(Ndmp)7(HNdmp)2O2] 1, containing an oxo double-cubane fragment [Sn7(Ndmp)6O2] coordinated to
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a9ec97cc32af489ef3c093b8f48818da
https://doi.org/10.1039/b101247i
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9
Geometric control of cage architecture; observation of ligand-selective behaviour in the structures of [{As2(NCy)4}2M4] (M = Na, Cu; Cy = C6H11)
Autor: Paul R. Raithby, Dominic S. Wright, Alan Bashall, Michael A. Beswick, Mary McPartlin, Sara J. Kidd, Eilis A. Harron, Alexander Steiner, Alexander D. Hopkins
Publikováno v: Chemical Communications. :1145-1146
The structure of [{As2(NCy)4}2Cu4] reveals a dramatic change in the metal coordination mode compared to that found in the Sb analogue [{Sb2(NCy)4}2Cu4], resulting in the distortion of the Cu4 core from a square-planar to a butterfly shape and providi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::68ed7f1cec04e91dec5df7ed9912bc1e
https://doi.org/10.1039/a903010g
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10
Synthesis and structure of [{As2(NCy)4}2Li4], containing an imido As(III) dianion
Autor: Dominic S. Wright, Michael A. Beswick, Eilis A. Harron, Paul R. Raithby, Alexander D. Hopkins
Publikováno v: Journal of the Chemical Society, Dalton Transactions. :107-108
Reaction of [As(NMe2)3] with CyNH2 (1∶1 equivalents), followed by the addition of [CyNHLi] (1 equivalent) gives the heterobimetallic cage complex [{As2(NCy)4}2Li4], the first example of a complex containing a imido As(III) anion; the missing link i
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8058712c2f906d1c0014b208a4310186
https://doi.org/10.1039/a808214f
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