A Stable Homoleptic Divinyl Tetrelene Series

Autor: Eike Dornsiepen, Michael J. Ferguson, Inke Siewert, Lucas A. Paul, Samuel R. Baird, Yuqiao Zhou, Linkun Miao, Matthew M. D. Roy, Eric Rivard

Publikováno v: Chemistry (Weinheim an Der Bergstrasse, Germany)

The synthesis of the new bulky vinyllithium reagent (MeIPr=CH)Li, (MeIPr=[(MeCNDipp)2C]; Dipp=2,6‐iPr2C6H3) is reported. This vinyllithium precursor was found to act as a general source of the anionic 2σ, 2π‐electron donor ligand [MeIPr=CH]−.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0cc51004b59858761f6f09822d44b6a0
https://doi.org/10.1002/chem.202100969

[{(PhSn)3SnS6}{(MCp)3S4}] (M = W, Mo): Minimal Molecular Models of the Covalent Attachment of Metal Chalcogenide Clusters on Doped Transition Metal Dichalcogenide Layers

Autor: Ralf Tonner, Fabian Pieck, Stefanie Dehnen, Eike Dornsiepen

Publikováno v: Journal of the American Chemical Society. 141:16494-16500

With the aim to mimic the yet unknown covalent deposition of metal chalcogenide clusters on transition metal dichalcogenide (TMDC) MoS2 or WS2 layers, and thereby explore the interaction between the two systems and potential consequences on physical

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c03f6a0c28b03da7b5b981f633dd71f8
https://doi.org/10.1021/jacs.9b09209

Coordination chemistry of organometallic or inorganic binary group 14/16 units towards d-block and f-block metal atoms

Autor: Niklas Rinn, Eike Dornsiepen, Eugenie Geringer, Stefanie Dehnen

Publikováno v: Coordination Chemistry Reviews. 380:136-169

Multinary complexes and clusters that combine transition metal or lanthanoid atoms with main group (semi-)metal atoms and chalcogenides provide a large variety of structural and electronic properties, which is why they have been subject to an enormou

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::52894432d9389a2dcd2aba8e856c8fbc
https://doi.org/10.1016/j.ccr.2018.09.001

Click reactions and intramolecular condensation reactions on azido-adamantyl-functionalized tin sulfide clusters

Autor: Stefanie Dehnen, Annikka Engel, Eike Dornsiepen

Publikováno v: Inorganic Chemistry Frontiers. 6:1973-1976

Herein, we present the synthesis of peptide-decorated organotin sulfide clusters via strain-promoted azide–alkyne cycloaddition. Overall, the target compounds are accessed in three major steps. The first step represents the synthesis of azide-termi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::368a6919fb4fbab265a7bb5c2bd70e03
https://doi.org/10.1039/c9qi00424f

Generating large starting configurations for molecular Reverse Monte Carlo modelling of an unique non-linear optical amorphous solid

Autor: Michael T. Wharmby, Wolf Christian Pilgrim, Benedict Paulus, Stefanie Dehnen, Eike Dornsiepen, Shinya Hosokawa, Benjamin D. Klee

Publikováno v: Journal of physics communications 4(3), 035004-(2020). doi:10.1088/2399-6528/ab756c
'Journal of Physics Communications ', vol: 4, pages: 035004-1-035004-7 (2020)

Journal of physics communications 4(3), 035004 - (2020). doi:10.1088/2399-6528/ab756c
We report on the recent advances regarding the source code optimization of Reverse Monte Carlo modelling used in scattering data analysis of an amorphous molec

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1ffdf1b4856afdf8a63e32df0292305
https://bib-pubdb1.desy.de/record/441627