Zobrazeno 1 - 3
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pro vyhledávání: '"Ei-ichi Sudo"'
Publikováno v:
Organic Letters. 12:2734-2737
Directed lithiation of N-benzenesulfonyl-3-bromopyrrole (1) with LDA in THF at -78 degrees C generated C-2 lithio species 3 selectively. Reactions of 3 with reactive electrophiles produced the corresponding 2-functionalized pyrroles 4. On the other h
Publikováno v:
Tetrahedron. 64(2):328-338
Palladium-catalyzed Suzuki--Miyaura coupling of N-benzenesulfonyl-3,4-dibromopyrrole with a variety of arylboronic acids gave the corresponding 3,4-diarylpyrroles in high yields. The 3,4-differentially arylated pyrroles could also be prepared by step
Publikováno v:
ChemInform. 41
The formation of the 2- or 5-substituted pyrroles is determined by a nature of the electrophiles used and in some cases the temperature.