Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis

Autor: Richard J. Lewis, Edwin N. Ntainjua, David J. Morgan, Thomas E. Davies, Albert F. Carley, Simon J. Freakley, Graham J. Hutchings

Publikováno v: Catalysis Communications, Vol 161, Iss , Pp 106358- (2021)

The direct synthesis of hydrogen peroxide from molecular H2 and O2 offers an attractive alternative to the current means of production of this powerful oxidant, on an industrial scale. Herein we investigate the role of nitric acid addition, during ca

Externí odkaz: https://doaj.org/article/1aee3e00a3354e378f0686e16fc30a30

Effect of Reaction Conditions on the Direct Synthesis of Hydrogen Peroxide with a AuPd/TiO2 Catalyst in a Flow Reactor

Autor: Jacob A. Moulijn, Graham J. Hutchings, Edwin N. Ntainjua, Marco Piccinini, Jennifer K. Edwards, Simon J. Freakley

Publikováno v: ACS Catalysis. 3:487-501

The direct synthesis of hydrogen peroxide (H2O2) represents a potential alternative to the currently industrially used anthraquinone process, and Au–Pd catalysts have been identified as effective catalysts. To obtain a direct process, a detailed un

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a38e5fd76e8dfbd32f1cff6189a3b586
https://doi.org/10.1021/cs400004y

Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity

Autor: Albina Y. Borisevich, Qian He, Jennifer K. Edwards, David A. Crole, Albert Frederick Carley, Jonathan H. Harrhy, Simon J. Freakley, Graham J. Hutchings, David J. Morgan, Edwin N. Ntainjua, Christopher J. Kiely, Li Lu

Publikováno v: Freakley, S J, He, Q, Harrhy, J H, Lu, L, Crole, D A, Morgan, D J, Ntainjua, E N, Edwards, J K, Carley, A F, Borisevich, A Y, Kiely, C J & Hutchings, G J 2016, ' Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity ', Science, vol. 351, no. 6276, pp. 965-968 . https://doi.org/10.1126/science.aad5705

Direct hydrogen peroxide synthesis Hydrogen peroxide is synthesized industrially without direct contact of hydrogen and oxygen in order to achieve high concentrations. For many applications, only dilute aqueous solutions are needed. Freakley et al. r

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::64e83783d3fc9db0bcec016e18729e17
https://purehost.bath.ac.uk/ws/files/187509965/hutchingsmtedit_Sf_CJK_SF_GH.pdf

Direct synthesis of hydrogen peroxide using Au–Pd-exchanged and supported heteropolyacid catalysts at ambient temperature using water as solvent

Autor: Jennifer K. Edwards, Simon J. Freakley, Graham J. Hutchings, Edwin N. Ntainjua, Marco Piccinini, James Charles Pritchard, Albert Frederick Carley

Publikováno v: Green Chem.. 14:170-181

The direct synthesis of hydrogen peroxide from molecular H2 and O2 represents a green and economic alternative to the current anthraquinone process used for the industrial production of H2O2. In order for the direct process to compete with the anthra

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::05cf2198181c3ad88060e2e9ef17cbe7
https://doi.org/10.1039/c1gc15863e

The Influence of Platinum Addition on Nano-Crystalline Ceria Catalysts for the Total Oxidation of Naphthalene a Model Polycyclic Aromatic Hydrocarbon

Autor: Benjamín Solsona, Tomás García, Stuart Hamilton Taylor, Edwin N. Ntainjua, Thomas E. Davies

Publikováno v: Catalysis Letters. 141:1732-1738

The effect of adding Pt to a highly active ceria polycyclic aromatic hydrocarbon total oxidation catalyst has been investigated for the oxidation of naphthalene. The addition of Pt to ceria suppressed the performance of the catalyst for total oxidati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::46abc36fc6733d30cbb4f8eaa7ad41a1
https://doi.org/10.1007/s10562-011-0710-3