Zobrazeno 1 - 10
of 157
pro vyhledávání: '"Edwin J. Hart"'
Publikováno v:
The Journal of Physical Chemistry A. 102:2667-2672
Thermal or hydrogen peroxide initiated decomposition of acidic aqueous ozone is described as a chain process propagated by OH and O2-/HO2 radicals. In the absence of H2O2 added, the chain is initiated by surface-catalyzed formation of H2O2. Surface-d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ea51b09dd99e1a87ce6f250f533c0d0a
https://doi.org/10.1021/jp9721053
https://doi.org/10.1021/jp9721053
Publikováno v:
The Journal of Physical Chemistry. 96:1005-1009
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::87e79806364eb56ef3e655117c129c93
https://doi.org/10.1021/j100181a084
https://doi.org/10.1021/j100181a084
Publikováno v:
Environmental Science & Technology. 25:1589-1596
The primary step in the thermal decomposition of acidic aqueous ozone solutions is the dissociation reaction: O 3 ⇄O+O 2 . This reaction is supported by the retarding effect of O 2 on the decomposition rate, by our activation energy measurements, E
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::93490fafcacf4aa923ee4a5c8184d054
https://doi.org/10.1021/es00021a010
https://doi.org/10.1021/es00021a010
Publikováno v:
International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry. 36:511-516
Water was irradiated with 300 kHz ultrasound under an argon atmosphere containing various amounts of methane and ethane. Limited studies were also made on ethylene, acetylene, propane and butane. The methane and ethane irradiations were carried out o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::93eec507a04f59e90691cefb8d6a2559
https://doi.org/10.1016/1359-0197(90)90198-q
https://doi.org/10.1016/1359-0197(90)90198-q
Publikováno v:
The Journal of Physical Chemistry. 94:284-290
Water was irradiated with 1 MHz ultrasound (about 2 W/cm{sup 2}) under mixtures of argon and acetylene of various compositions. A few experiments were performed using deuterated acetylene. Acetylene is rapidly consumed, the maximum rate occurring at
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5d16a8ef484b31e8efae12ae4c45b0ab
https://doi.org/10.1021/j100364a047
https://doi.org/10.1021/j100364a047
Publikováno v:
International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry. 29:399-403
The free-radical initiated chain decomposition of aqueous O 3 -O 2 solutions has been studied as a function of dose rate and O 3 concentration in the pH range, 2.0–7.0. At dose rates of 10 rad s − or less, extensive chain decomposition of O 3 occ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::59218bcd15f8cb3f9854dcfb6ab5ff44
https://doi.org/10.1016/1359-0197(87)90013-0
https://doi.org/10.1016/1359-0197(87)90013-0
Publikováno v:
The Journal of Physical Chemistry. 88:4144-4147
In slightly alkaline solution the ozonide radical ion, O/sub 3//sup -/, forms as a product of the hydroxyl radical reaction with ozone. For each O/sub 3//sup -/ formed, two O/sub 3/ molecules are consumed. In acid solution the product of this reactio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a69531a9befa873dda5de2af3254257f
https://doi.org/10.1021/j150662a058
https://doi.org/10.1021/j150662a058
Publikováno v:
The Journal of Physical Chemistry. 81:1363-1367
Formation of radical cations from the OH adducts of methylated benzenes in acidic aqueous solutions is demonstrated. The radical cation is formed as an intermediate species in the water elimination reaction in which the OH adduct is transformed into
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::763294a7a3e53965e2a416a58046456a
https://doi.org/10.1021/j100529a005
https://doi.org/10.1021/j100529a005
Autor:
Weldon G. Brown, Edwin J. Hart
Publikováno v:
Radiation Physics and Chemistry (1977). 15:163-167
O(3P) atom formation in irradiated aqueous solutions was studied in the BrO3- concentration range from 0.01 to 2.0 mol dm-3 by measuring the ethylene resulting from the O(3P) atom reaction with cyclopentene (CP). Reaction of O(3P) with BrO3− attain
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1ab329d0576aeea37fc2abd70766bac2
https://doi.org/10.1016/0146-5724(80)90127-2
https://doi.org/10.1016/0146-5724(80)90127-2
Autor:
Edwin J. Hart, Arnim Henglein
Publikováno v:
The Journal of Physical Chemistry. 89:4342-4347
On etudie l'influence de l'oxygene sur la formation de peroxyde d'hydrogene en irradiant des solutions de iodure de potassium et de formiate de sodium sous divers melanges d'argon et d'oxygene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a45465ce8a3e0a5f95500f254fe07bc8
https://doi.org/10.1021/j100266a038
https://doi.org/10.1021/j100266a038