Zobrazeno 1 - 10
of 100
pro vyhledávání: '"Edward W, Castner"'
Publikováno v:
The Journal of Physical Chemistry C. 126:13936-13945
We report studies of the vacuum interfacial structure of a series of 1-methyl-3-alkylimidazolium bis(perfluoroalkanesulfonyl)imide ionic liquids (ILs) and predict and explain their Fresnel-normalized X-ray reflectivity. To better interpret the result
Autor:
Fabrizio Lo Celso, Giovanni B. Appetecchi, Elisabetta Simonetti, Man Zhao, Edward W. Castner, Uwe Keiderling, Lorenzo Gontrani, Alessandro Triolo, Olga Russina
Publikováno v:
Frontiers in Chemistry, Vol 7 (2019)
Here we report a thorough investigation of the microscopic and mesoscopic structural organization in a series of triphilic fluorinated room temperature ionic liquids, namely [1-alkyl,3-methylimidazolium][(trifluoromethanesulfonyl)(nonafluorobutylsulf
Externí odkaz:
https://doaj.org/article/8b9214fd92f147a586143723926e10c4
Autor:
Edward W. Castner
Publikováno v:
Proc Natl Acad Sci U S A
Polymers and polymeric materials exhibit flexibility between neighboring components of their molecular chains, permitting disordered conformations relative to the crystalline state. The disordered chain conformations lead to entanglements between nei
Publikováno v:
Journal of the American Chemical Society. 139:14568-14585
The present work seeks to better understand the role of solute diffusion and solvation dynamics on bimolecular electron transfer in ionic liquids (ILs). Steady-state and time-resolved measurements of the reductive fluorescence quenching of five fluor
Autor:
Sharon I. Lall-Ramnarine, Eddie D. Fernandez, James F. Wishart, Man Zhao, Chanele Rodriguez, Surajdevprakash B. Dhiman, Rahonel Fernandez, Nicole Zmich, Edward W. Castner
Publikováno v:
Journal of The Electrochemical Society. 164:H5247-H5262
Publikováno v:
The Journal of Physical Chemistry B. 121:174-179
The behavior in the bulk and at interfaces of biphilic ionic liquids in which either the cation or anion possesses moderately long alkyl tails is to a significant degree well understood. Less clear is what happens when both the cation and anion posse
Autor:
Quintin R. Sheridan, Edward W. Castner, Joan F. Brennecke, Oscar Morales-Collazo, Seungmin Oh, Edward J. Maginn
Publikováno v:
The Journal of Physical Chemistry B. 120:11951-11960
A combination of X-ray scattering experiments and molecular dynamics simulations were conducted to investigate the structure of ionic liquids (ILs) which chemically bind CO2. The structure functions were measured and computed for four different ILs c
Publikováno v:
The Journal of Chemical Physics. 153:214501
Ionic liquids (ILs) with long alkyl substituents are amphiphilic, which leads to a bicontinuous liquid structure. The strongly interacting anionic and cationic head groups form a long range charge network, with the hydrocarbon tails forming a nonpola
Publikováno v:
The Journal of chemical physics. 148(19)
Zwitterionic liquids (Zw-ILs) have been developed that are homologous to monovalent ionic liquids (ILs) and show great promise for controlled dissolution of cellulosic biomass. Using both high energy X-ray scattering and atomistic molecular simulatio