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of 10
pro vyhledávání: '"Edward M, Treadwell"'
Publikováno v:
Chemical Communications. 55:1786-1789
Benzobis(imidazolium) salts ([BBI-H2-R4]2+, R = alkyl, aryl) interact with crown ethers through a combination of hydrogen bonds, ion–dipole, and π–π stacking interactions to form starburst [24]pseudo-rotaxanes. This new recognition motif allows
Autor:
Bret R. Van Ausdall, Edward M. Treadwell, Joel S. Southern, Ellen A. Keiter, Kraig A. Wheeler, Richard L. Keiter, Michael F. Cuddy
Publikováno v:
Organometallics. 37:3742-3749
The linkage isomers [(OC)5W{κ1-PPh2CH2CH(PPh2)[P(p-tol)2]}] 3a, [(OC)5W{κ1-P(p-tol)2CH(PPh2)CH2PPh2}] 3b, and [(OC)5W{κ1-PPh2CH[P(p-tol)2]CH2PPh2}] 3c isomerize at ambient temperatures to give a mixture of the three isomers in equilibrium. Rates o
Publikováno v:
Chemical communications (Cambridge, England). 55(12)
Benzobis(imidazolium) salts ([BBI-H2-R4]2+, R = alkyl, aryl) interact with crown ethers through a combination of hydrogen bonds, ion-dipole, and π-π stacking interactions to form starburst [24]pseudo-rotaxanes. This new recognition motif allows the
Publikováno v:
The Journal of Organic Chemistry. 64:8718-8723
Publikováno v:
ChemInform. 34
[reaction: see text] A strategy for synthesis of the hexahydroxanthene moiety of the natural products schweinfurthin A, B, and D is described. The relative stereochemistry in the key cationic cyclization step is established through the preference of
Publikováno v:
Journal of natural products. 62(2)
A new prenylated benzoic acid, arieianal [3,4-dihydroxy-5-(E,E, E-11'-formyl-3',7',15'-trimethylhexadeca-2',6',10', 14'-tetraenyl)benzoic acid, 1], has been isolated from the leaves of Piper arieianum and assigned this structure on the basis of its s
Autor:
Edward M. Treadwell
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 62:o5899-o5900
The molecule of the title compound [systematic name: 3-(4-methylphenyl)-1-phenylprop-2-enone], C16H14O, displays a significant deviation from planarity; the torsion angle of the carbonyl oxygen and the three enone C atoms is 16.3 (3)°, while t
Autor:
Tung Yin Lin, Edward M. Treadwell
Publikováno v:
Journal of Chemical Education. 85:1541
An experiment is described involving the nitration of ortho or meta monosubstituted benzoic acids (XC6H4CO2H, X = Halogen, Me, OH, or OMe) and monochlorinated acetanilides with nitric acid to determine the regioselectivity of addition by 1H NMR spect
Autor:
Thomas P. Clausen, Edward M. Treadwell
Publikováno v:
Ethnobotany Research and Applications. 6:319
Hedysarum mackenzii (wild sweet pea, bear root) is widely regarded as toxic and warnings about confusing it with its edible cousin H. alpinum (Eskimo potato) abound. To find the chemical basis for this claim, we performed an exhaustive comparison of
Autor:
Edward M. Treadwell, T. Howard Black
Publikováno v:
Journal of Chemical Education. 82:1046
The differences and similarities in the physical behavior of enantiomers and diastereomers can easily be demonstrated using the commercial stereoisomers (?)-menthol, (+)-menthol, (+)-isomenthol, and (+)-neomenthol. Thin-layer chromatography and melti