Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Edward J. Stoebenau"'
Publikováno v:
Organometallics. 29:1750-1760
The reaction of vinyl chloride (VC) with (α-diimine)PdMe+ species yields (α-diimine)PdCl(propene)+. Isotope labeling experiments using the deuterium-labeled vinyl chlorides 1-VC-d1 and Z-VC-d1 combined with DFT computations establish that this reac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::31b2d031ae4b7974d3262164e4a69e65
https://doi.org/10.1021/om1000925
https://doi.org/10.1021/om1000925
Autor:
Richard F. Jordan, Edward J. Stoebenau
Publikováno v:
Journal of Organometallic Chemistry. 691:4956-4962
The generation and properties of the Cp2Zr{CH(SiMe3)2}+ cation are described. An X-ray crystallographic analysis shows that the carborane salt [Cp2Zr{CH(SiMe3)2}][HCB11Me5Br6] contains an agostic Zr–μ-Me–Si interaction in the solid state. Low te
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::739b34ed94e7f4f7c404ddf0d527a210
https://doi.org/10.1016/j.jorganchem.2006.08.033
https://doi.org/10.1016/j.jorganchem.2006.08.033
Autor:
Richard F. Jordan, Edward J. Stoebenau
Publikováno v:
Organometallics. 25:3379-3387
Addition of alkynes to [Cp‘2Zr(OtBu)][B(C6F5)4] (Cp‘ = C5H4Me, 2) at low temperature in CD2Cl2 solution yields equilibrium mixtures of Cp‘2Zr(OtBu)(RC⋮CR‘)+ (3a−g), 2, and free alkyne. The 13C NMR ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a43a4c8144482657da9a20560033908f
https://doi.org/10.1021/om050947f
https://doi.org/10.1021/om050947f
Autor:
Carla Slebodnick, Xu Cheng, Frank R. Fronczek, Edward J. Stoebenau, Paul A. Deck, and Damon R. Billodeaux
Publikováno v:
Organometallics. 19:5404-5409
(EtMe2SiC5H4)CpZrCl2 (5) reacts with BBr3 in 1,2-dichloroethane (reflux, 24 h) to afford a 4:1 mixture of (EtMeBrSiC5H4)CpZrBr2 (10) and (BrMe2SiC5H4)CpZrBr2 (11) in a nearly quantitative conversion. Similarly, (tBuMe2SiC5H4)CpZrCl2 (6) reacts with B
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7fb7f2c4b8d9f6884c0b7e6aa6978985
https://doi.org/10.1021/om0005452
https://doi.org/10.1021/om0005452
Autor:
Edward J. Stoebenau, Richard F. Jordan
Publikováno v:
Journal of the American Chemical Society. 128(26)
This paper describes the generation and properties of nonchelated d(0) zirconocene-aryl-alkene and alkyne adducts that are stabilized by the presence of beta-SiMe(3) substituents on the substrates and the weak nucleophilicity of the -C(6)F(5) ligand.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e59edf5b5d6caafed051fbbf547e774
https://pubmed.ncbi.nlm.nih.gov/16802830
https://pubmed.ncbi.nlm.nih.gov/16802830
Autor:
Richard F. Jordan, Edward J. Stoebenau
Publikováno v:
Journal of the American Chemical Society. 126(36)
The generation and properties of nonchelated Zr-aryl-alkyne and Zr-aryl-alkene complexes that are stabilized by the presence of beta-Si-substituents in the alkyne and alkene ligands and fluorination of the aryl ligand are described. Reaction of [Cp'2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::45247d29adf5572277eaa4f840d1c9b4
https://pubmed.ncbi.nlm.nih.gov/15355096
https://pubmed.ncbi.nlm.nih.gov/15355096
Autor:
Richard F. Jordan, Edward J. Stoebenau
Publikováno v:
Journal of the American Chemical Society. 125(11)
This paper describes the synthesis of base-free (C5R5)2Zr(OtBu)+ cations, the direct observation of nonchelated alkene and alkyne adducts of these cations, and studies of the thermodynamic and dynamic properties of these novel species. Reaction of %@
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5176eb99b4830c8113924bf010849682
https://pubmed.ncbi.nlm.nih.gov/12630871
https://pubmed.ncbi.nlm.nih.gov/12630871