Zobrazeno 1 - 10
of 67
pro vyhledávání: '"Eduardo H. Staricco"'
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 123:1-5
The photolysis of perfluoropropyl fluoride and perfluoropropyl chloride vapour was studied in the 12.9–79.0 Torr and 6.1–40.7 Torr pressure ranges, using light of 232–240 and 254 nm, respectively. The products found were CF 3 CF 2 COF: CO, C 4
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 117:163-169
Photolysis of CF3COCl in the presence of O2 yields the radical CF3O, which then reacts in the presence of CO and O2 to yield a variety of CF3-containing species initiated by the following reactions: CF 3 O+CO→CF 3 OCO CF 3 OCO+O 2 →CF 3 OC(O)O 2
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 115:199-206
The quenching rate constant kq of the excited states *Cr(bpy)33+ and *Cr(phen)33+ by several substituted phenols was investigated as a function of temperature using the time resolved luminescence quenching technique. The activation parameters showed
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 103:19-25
The photolysis at 254 nm of perfluoroacetyl chloride (CF3COCl) in the gas phase and with O2 in excess yielded CO2, CF2O, CF3OOOCF3, CF3COF and Cl2 as products. It was observed that the ratio of CF3COCl consumed to Cl2 formed was 2:1 and that the rate
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 86:27-31
The photolysis of perfluoroacetyl chloride vapour was studied in the pressure range 4.6–59.9 Torr and with addition of inert gas up to 535.2 Torr using light of 254 and 280 nm. The quantum yield for the decomposition of CF 3 COCl taken as Φ [CF 3
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
CF3 radicals were generated by the photolysis of perfluoroacetic anhydride. In the presence of pentafluorobenzene, the CF3 radicals react according to the following mechanism: It was found that the addition reaction (3) becomes reversible above ca. 4
Publikováno v:
ChemInform. 23
The reaction of CH2(1A1) with 1,1,2,2-tetrafluorocyclopropane was studied at 300 K and at pressures between 9.0 and 365.0 torr. Chemically activated 1-methyl-2,2,3,3-tetrafluorocyclopropane was formed and two competitive reaction paths, namely decomp
Publikováno v:
International Journal of Chemical Kinetics. 24:619-629
The reaction of CH2(1A1) with 1,1,2,2-tetrafluorocyclopropane was studied at 300 K and at pressures between 9.0 and 365.0 torr. Chemically activated 1-methyl-2,2,3,3-tetrafluorocyclopropane was formed and two competitive reaction paths, namely decomp